石墨烯在光催化水解制氢中的应用王保伟.pdfVIP

化 工 进 展 2012 年第31 卷第10 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·2245 · 进展与述评 石墨烯在光催化水解制氢中的应用 王保伟，孙启梅 （天津大学化工学院，绿色合成与转化教育部重点实验室，天津 300072 ） 摘 要：由于石墨烯优异的电子结构和电子传输性能，使得其在光催化领域的研究得到了广泛的关注。本文简 要介绍了最新以石墨烯为基础的复合光催化剂的制备方法及其在催化水分解制氢方面的应用，重点评述了石墨 烯及其氧化物、TiO2 与石墨烯类复合物、CdS 与石墨烯类复合物、含氧金属酸盐与石墨烯类复合物等的光催化 性能，简要说明了光敏化、贵金属负载、非金属掺杂等对复合物光催化性能的影响。最后，指出对于石墨烯与 纳米材料复合物的结构及光催化作用的机理都有待于进一步的研究，以便充分利用石墨烯的二维平面结构制得 具有较高光催化水解制氢活性的催化剂。 关键词：石墨烯；光催化；氢气 中图分类号：O 6.1 文献标志码：A 文章编号：1000 –6613 （2012 ）10 –2245 –08 Application of graphene in photocatalytic water splitting producing hydrogen WANG Baowei，SUN Qimei （Key Laboratory for Green Chemical Technology of Ministry of Education，School of Chemical Engineering and Technology，Tianjin University ，Tianjin 300072，China ） Abstract ：Graphene has drawn extensive attention in the field of photocatalysis due to its excellent electronic structure and electronic transmission performance. The latest development of graphene-based nanocomposite ，such as graphene and graphene oxide ，TiO2/graphene ，CdS/graphene and metallate/graphene ，in the application of water splitting for hydrogen was summarized. Photosensitization ，loading noble metal and doping nonmetal ，and how they influence the photocatalysis activity of graphene-based nanocomposites were discussed. Finally ，the structure of graphene-based nanocomposite and its underlying mechanism of photocatalytic enhancement were two important factors needing further study. The photocatalysts with higher photocatalytic activity for water splitting producing H2 could be expected. Key words ：graphene