Pt-Mn3O4C as efficient electrocatalyst for oxygen evolution reaction in water electrolysis》.pdf

Electrochimica Acta 146 (2014) 119–124 Contents lists available at ScienceDirect Electrochimica Acta journa l home page : www.e /loca te/ele cta cta Pt-Mn O /C as efficient electrocatalyst for oxygen evolution reaction in 3 4 water electrolysis Zhuo-ying Li, Shu-ting Shi, Qi-sui Zhong, Chan-juan Zhang, Chang-wei Xu * Guangzhou Key Laboratory for Environmentally Functional Materials and Technology, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, PR China A R T I C L E I N F O A B S T R A C T Article history: Pt-Mn O catalysts with carbon black as conductive agent and support show a remarkable activity for 3 4 Received 3 June 2014 oxygen evolution reaction because of a synergistic effect between Pt and Mn O . The Pt-Mn O /C catalyst 3 4 3 4 Received in revised form 8 September 2014 with a weight ratio of Pt to Mn O of 3:1 gives the best performance. After loading with Mn O , the 3 4 3 4 Accepted 10 September 2014 binding energy value of Pt 4f and Mn 2p respectively has a positive and negative shift, which will Available online 19 September 2014 acceler