真空铝热还原炼锂新工艺中富锂熟料的制备.pdfVIP

第36卷第10期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol.36,No.10 2015 年 10 月 Journal of Northeastern University(Natural Science) Oct.20 1 5 doi:10.3969/j.issn.1005 -3026.2015.10.018 真空铝热还原炼锂新工艺中富锂熟料的制备 狄跃忠,唐成伟,赵 康,冯乃祥 (东 大学 材料与冶金学院,辽宁沈阳 110819) 摘 要:常压煅烧氢氧化锂、氧化铝和氧化钙混合物得到富锂熟料,真空铝热还原该熟料得到金属锂及 可制备氢氧化铝的12CaO•7Al O 型还原渣.研究了制团压力、煅烧温度、煅烧时间对煅烧烧损率及锂还原率 2 3 的影响.结果表明:在制团压力为30MPa,煅烧温度为750～800 ℃,煅烧时间为60 ～90min 的条件下,烧损率 基本保持在34%左右；该条件所得富锂熟料在还原温度1 100℃,还原时间90min,铝粉不过量的条件下进行 真空铝热还原得到锂还原率较高.该煅烧工艺适用于真空铝热还原炼锂新工艺中富锂熟料的制备. 键 词:氢氧化锂；真空；铝热还原；烧损率；锂还原率 中图分类号:T 826.3 文献标志码:A 文章编号:1005 -3026(2015)10-1449 -05 Preparation of Lithium-Rich Clinker in New Vacuum Aluminothermy Reduction of Lithium Process DI Yue-zhong,TANG Cheng-wei,ZHAO Kang,FENG Nai-xiang (School of Materials Metallurgy,Northeastern University,Shenyang 110819,China.Corresponding author:DI Yue-zhong,E-mail:diyz@smm.neu.edu.cn) Abstract:A new vacuum aluminothermy reduction of lithium process was developed,in which lithium hydroxide,alumina and calcium oxide mixture were used as raw materials.Lithium-rich clinker was prepared by calcining the mixture of raw materials.Metal lithium and reduction slag contained the 12CaO•7Al O which was used to form aluminum hydroxide were produced by the 2 3 vacuum aluminothermy reduction process.Effects of briquette pressure,calcination temperature and time on the burning loss rate and lithium reduction rate were investigated.The result showed that the burning loss rate remained about 34% under the conditions of briquette pressure 30MPa, calcination temperature 750～800 ℃ and calcination time 60 ～90min.The lithium reduction rate was relatively high when the lithium-rich clinker obtained under the ab