bnt基无铅压陶瓷的制备与固溶改性研究.pdfVIP

材料的反铁电相区域增加，获得较优的铁电性。材料的弛豫度随 CT 相的引入逐渐增强。 对于 (1-x)(0.92BNT-0.06BT-0.02ST)-xLiSbO ( 简写为 0.92BNT-0.06BT-0.02ST-100x 3 SL)体系材料，XRD 图谱表明，少量的 SL 引入不会影响 0.92BNT-0.06BT-0.02ST 的晶体 结构，当 x≥0.06mol% 时，陶瓷材料中出现第二相。SEM 显示 SL 促进了 0.92BNT- 0.06BT-0.02ST 晶粒的生长，介电温度特性曲线显示，材料逐渐由两个介电反常峰逐渐 转变为一个宽化的介电峰，随 SL 的引入，电滞回线逐渐由类似于反铁电体的“双电滞回 线” 向细长的单电滞回线转变。 关 键 词：钛酸铋钠基；钙钛矿结构；固溶；弛豫相变 研究类型：应用基础研究 Subject : Study on Preparation and Property Improvement of BNT-based Lead-free Piezoelectric Ceramics Specialty : Materials Physics and Chemistry Name : Mu Wenfang (Signature) Instructor: Du Huiling (Signature) ABSTRACT Sodium bismuth titanate(Bi Na TiO , abbreviated as BNT), is a kind of A-site 0.5 0.5 3 substituted perovskite-type ferroelectric. In this paper, BNT was choosed as the research base material. In order to improve the properties of piezoelectric and ferroelectric and achieve the practical purpose of BNT ceramics, a series of solid solution modification research had been taken on BNT ceramics according to the research ideas of lead based piezoelectric ceramics. The dense lead-free piezoelectric ceramics (0.944-x)Bi Na TiO -0.056BaTiO -x SrTiO 0.5 0.5 3 3 3 (abbreviated as 0.944BNT-0.056BT-100x ST) and (1-x)(0.93Na Bi TiO -0.07BaTiO )- 0.5 0.5 3 3 xKNbO (abbreviated as 0.93B