《Electrochemical Properties of Sn Doped AB5 Non-Stoichiometric Hydrogen Absorbing Alloys-Ⅱ》.pdfVIP
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《Electrochemical Properties of Sn Doped AB5 Non-Stoichiometric Hydrogen Absorbing Alloys-Ⅱ》.pdf
JOURNAL OF RARE EARTHS 200 1 VoI . 19 No . 1
Electrochemical Properties of Sn Doped AB5 Non-Stoichiometric
!
Hydrogen Absorbing Alloys- !
(王志兴), (李新海), (陈启元),
WANG Zhi-xing LI Xin-hai CHEN Oi-yuan
(郭华军), (彭文杰), (郭炳昆)
GUO Hua-jun PENG Wen-jie GUO Bin-kun
( , ,
Institute of Metallurgical Physico-Chemistry and Materials Central South Uniuersity of Technology
, , )
Changsha 410083 China
: ,
Abstract The effects of some substituting eIements on the specific discharge capacity activation and cycIing Iife of
AB5 non-stoichiometric hydrogen absorbing aIIoys were studied eIectrochemicaIIy . ResuIts show that the characteris-
tics of hydrogen absorbing aIIoys under Iow current density are greatIy improved through the substitution of Ni by
, , , , ( ) , ( ) ( )
sn Co and Mn . Three hydrogen storage aIIoys i . e . La Nisn 5 . 14 La NisnCo 5 . 12 and La NisnMn 5 . 12 have
the higher specific capacity and easy activation . However ,
AI in the aIIoy shows the opposite effect on the eIectro-
, ( )
chemicaI properties . Under high current density the discharge capacity and potentiaI of La Nisn 5 . 14 is superior to
( ) ( ) , ( )
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