《Enhancing the Deactivation Durability of Nano-sized HZSM-5 for Aromatization by Adjusting its Ratio of LewisBrφnsted Acid Sites》.pdfVIP

Chinese Chemical Letters Vol. 15, No. 9, pp 1123-1126, 2004 1123 /journal/ccl.html Enhancing the Deactivation Durability of Nano-sized HZSM-5 for Aromatization by Adjusting its Ratio of Lewis/Brf nsted Acid Sites 1 1 1 Zhou Bo XU , Hong Chen GUO *, Xiang Sheng WANG , 1 2 2 Pei Qing ZHANG , Le Ping ZHAO , Yong Kang HU 1 Department of Catalytic Chemistry and Engineering State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 2Fushun Research Institute of Petroleum and Petrochemicals, Fushun 113001 Abstract: Ratio of Lewis/Brfnsted acid sites (Cl/Cb) on the surface of nano-sized HZSM-5 was successfully manipulated by means of steaming and acid leaching. Significant enhancement of the deactivation durability of nano-sized HZSM-5 in the aromatization of fluid catalytic cracking (FCC) gasoline olefins seems to be closely related to the increase of Lewis/Brfnsted acid sites ratio. Keywords: Lewis acid, Brfnsted acid , nano-sized HZSM-5, aromatization, gasoline. Nano-sized zeolites have special physicochemical properties compared to micron-sized ones1,2 . Recently, we have demonstrated the effectiveness and the remarkable deactivation durability of nano-sized HZSM-5 in converting the olefins of FCC gasoline to