《Synthesis and Structural Characterization of Gd(Ⅱ) Coordination Polymer [Gd2(μ-phth)3(b-pd)(H2O)5]n》.pdfVIP
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《Synthesis and Structural Characterization of Gd(Ⅱ) Coordination Polymer [Gd2(μ-phth)3(b-pd)(H2O)5]n》.pdf
25 卷4 期 JIEGOU HUAXUE Vol. 25, No. 4
2006. 4 Chinese J. Struct. Chem. 453~458
Synthesis and Structural Characterization of Gd( )
Coordination Polymer [Gd (µ-phth) (b-pd)(H O) ]
2 3 2 5 n
HUANG Mei-huaa, b LIU Pinga WANG Jiana
CHEN Yuna, b LIU Zhenga, b
a (Fujian Institute of Research on the Structure of Matter, The Chinese
Academy of Sciences,Fuzhou, Fujian 350002, China)
b
(Graduate School of the Chinese Academy of Sciences, Beijing 100039, China)
ABSTRACT A new Gd(II) complex [Gd (µ-phth) (b-pd)(H O) ] (phth = o-phthalato, b-pd = N,N-
2 3 2 5 n
bipyridine) has been synthesized by the reaction of GdO with o-phthalate, H O and 2,2 -bipyridine.
′
2 2
The crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of triclinic,
space group P 1 with a = 11.82920(10), b = 13.53550(10), c = 13.7381(2) Å, α = 88.99, β= 66.9120(10),
γ = 66.2370(10)°, V = 1826.02(3) Å3 3
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