The generation kinetics of natural gases in the Kela-2 gas field from the Kuqa Depression, Tarim Basin, northwestern China-论文.pdf

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The generation kinetics of natural gases in the Kela-2 gas field from the Kuqa Depression, Tarim Basin, northwestern China-论文.pdf

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Chin．J．Geochem．(2013)32：157—169 D0I：l0．1007／sll631-0l3-0618-2 Thegenerationkineticsofnaturalgasesinthe Kela-2gasfieldfrom theKuqaDepression， Tarim Basin，northwesternChina LIXianqing’，FENGSongbao，XIAOXianming ，TANGYongchun ，XIAOZhongyao，MIJingkui， TIANHui．‘LIU Dehan．‘andSHEN Jiagui‘ StateKeyLaboratoryofCoalResourcesandSafeMining,ChinaUniversityofMiningandTechnology,Beoing100083，China StateKeyLaboratoryofOrganicGeochemis GuangzhouInstituteofGeochemistry,ChineseAcademyofSciences，Guangzhou510640,China Power,EnvironmentalandEnergyResearchCenter,CalfiorniaInstituteofTechnology,738ArrowGrandCircle,Covina,Calfiornia91722,USA ResearchInstituteofExplorationandDevelopment,TarimOilfieldCompany,PetroChina,Korla841000,China ResearchInstituteofPetroleumExplorationandDevelopment,PetroChina,Beoing100083，China ’Correspondingauthor,E-mail：Lixa@cumtb．edu．cn ReceivedFebruary15，2012；acceptedMarch10，2012 ◎SciencePressandInstituteofGeochemistry,CASandSpringer-VerlagBerlinHeidelberg2013 Abstract TheKela2‘gasfield，found in theKuqaDepression oftheTarim Basin，northwestern China，isa large-sizeddrygasfield(C1／C15=0．992—0．999)andcharacterizedbyultra—highpressure(pressurefactorupto 2．0—2．2)．Thepyrolysisexperimentwascarriedoutunderisothermalgold-utbeclosedsystem，withsamplescollected from theJurassiccoal，JurassicmudstoneandTriassicmudstoneintheKuqaDepression．Theresultofgasyield showedthattheMiddleandLowerJurassicsourcerockshavehighergasgenerationpotentialthantheTriassic sourcerocks．Thekineticmodelingofgasgenerationandmethanecarbonisotopefractionationsuggestedthatthe Kela-·2gasesbelongtotheproductsofhigh-·overmautrestagesandweremainlyderivedrfom theMiddleandLower Jurassiccoal—bearingsrtata．TheTriassicsourcerocksmadeaminorcontributiontotheKela一2gases．TheKela-2 gaseschieflygeneratedrfom coal-bearingsourcerockswithR0valuesfrom 1-3％ to2．5％，andthusprimarilyaccu- mulatedafter5Ma． Keywords naturalgas；pyrolysisexperiment；gasgenerationkinetics；carbonisotopefractionation；Kela一2ga