高铝粉煤灰制备拟薄水铝石的比表面积与孔隙特性分析.docVIP

高铝粉煤灰制备拟薄水铝石的比表面积与孔隙特性分析 张伟光张廷安冯伟吕国志刘燕 （东北大学 多金属共生矿生态化利用教育部重点验室沈阳 110819） 摘要：高铝粉煤灰熟料经预脱硅碱石灰烧结、溶出、二次脱硅后溶液经碳分及种分后得到拟薄水铝石产品，采用低温氮气吸附法分析比表面积以及孔结构。结果表明碳分法和种分法制备拟薄水铝石的等温吸附线均属Ⅳ类，晶粒之间的孔隙以中孔为主，等温吸附曲线滞后环类似于H4型，是狭缝孔。碳分BET比表面积略大于种分产品，然而其BJH吸附累积总孔孔容与BJH吸附平均孔径略低于种分产品，两种产品的物化指标均优于普通拟薄水铝石样品。 关键词：高铝粉煤灰；拟薄水铝石；比表面积；孔容积；孔径TF821 文献标志码：A 文章编号：1007-7545（2015）11-0000-00 Specific Surface Area and Pore Characteristics Analysis of Pseudo-boehmite Prepared by High-alumina Fly Ash ZHANG Wei-guang, ZHANG Ting-an, FENG Wei, LU Guo-zhi, LIU Yan (Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores of Ministry of Education, Northeastern University, Shenyang 110819, China) Abstract：Pseudo-oehmite (PB) product was prepared from sintered high-alumina fly ash clinker. Fly ash clinker was pretreated by deep desilication and sintering with soda lime, and twice-desilication solution was decomposed (carbonation decomposition and seed precipitation) to prepare PB. Specific surface areas and pore distribution of PB were analyzed by low-temperature nitrogen adsorption. The results show that adsorption isotherm curve of PB prepared by carbonation and seed precipitation process presents as type Ⅳ. Most of pores between grains are mesopore. Hysteresis loop of adsorption isotherm curve presents as slit pores similar to H4 type. BET specific surface area of carbonation decomposition product is bigger than that of seed precipitation. However, BJH pore volume and BJH pore size are smaller than those of seed precipitation product. Physical chemical indexes of two products are superior to common PB products. Key words: high-alumina fly ash; pseudo-boehmite; specific surface area; pore volume; pore size 粉煤灰中氧化铝含一般为17%~35%，部分地区更是超过40%，甚至达到60%，并且中国每年粉煤灰的排放量随着电力行业的发展而逐年增加[1]。目前，从粉煤灰中提取氧化铝主要为酸法、碱法以及酸碱联合法，其中应用较为成功的是预脱硅碱石灰烧结工艺然而其较长的流程以及较高的能耗，使其在制备冶金级氧化铝方面展现不出比传统铝土矿更好的经济优势[2-7]。基于此，作者所在团队利用预脱硅碱石灰烧结工艺中较强的溶液净化优势，提出了利用其两段脱硅后液进行分解（碳化分解、晶种分解）制备拟薄水铝石的新想法嫁接在预脱硅碱石灰烧结法的生产工艺中。 拟薄水铝石广泛应用于石油化工领域[8]，比表面积以及孔隙分布特性拟薄水铝石产品