水性丙烯酸酯乳液的合成及性能研究[J].pdfVIP

化 学 工 程 师 Sum 198 No.03 Chemical Engineer 2012 年第03 期 文章编号：1002-1124 （2012）03-0001-06 科 研 * 与 水性丙烯酸酯乳液的合成及性能研究 开 发 王晓明，王经文，李 晴，李淑琴 （南京航空航天大学材料科学与技术学院，江苏南京 211106） 摘 要：以双丙酮丙烯酰胺（DAAM）为功能性单体，采用预乳化半连续种子乳液聚合法合成水性丙烯酸 酯乳液，添加己二酸二酰肼（ADH）为交联剂，构成室温自交联体系。考察了DAAM、ADH 用量对乳液及其乳胶 膜性能的影响。用傅里叶红外光谱仪（FT- IR）对交联反应进行了表征。通过差示扫描量热法、力学性能和耐溶 剂性能的测试等方法研究了乳液和乳胶膜的性能。结果表明，当DAAM 用量为2.4%~3.5% ，ADH 与DAAM 的 当量比为1~1.2 时，乳液和乳胶膜的综合性能较好。 关键词：水性；丙烯酸酯乳液；室温自交联；双丙酮丙烯酰胺 中图分类号：TQ630 文献标识码：A Synthesis and characterization of water-borne acrylate emulsion* WANG Xiao-ming ，WANG Jing-wen ，LI Qing ，LI Shu-qin （College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106 ，China） Abstract ：An aqueous ambient crosslinkable polymer acrylic emulsion was obtained by adding adipic acid dihydrazide （ADH）to the acrylate emulsion incorporating diacetone acrylamide （DAAM）. The influences of amounts of DAAM and ADH on the properties of polymerization emulsion and its paint film were discussed. The crosslinking reaction was characterized by Fourier Transform Infrared （FT-IR）. Differential scanning calorimetry physico-mechanical properties and solvent resistance of the film were investigated. The results showed that the emulsion and latex film had better comprehensive properties when the amount of DAAM was 2.4%~3.5% and the equivalence ratio of ADH/DAAM ranging from 1 to 1.2. Key words ：water-borne ；acrylate emulsion ；ambi