克酮酸菁染料研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201307052 学术动态 有机化学 Chinese Journal of Organic Chemistry REPORT 克酮酸菁染料研究进展 张守鑫 杨小兵* 温晓红 丁松涛 王安邦 (防化研究院国民核生化灾害防护国家重点实验室 北京 100191) 摘要 克酮酸菁染料是有机功能染料菁类染料中的重要成员, 由于其在近红外区具有吸收峰强烈且尖锐、摩尔吸光系 数大、光热稳定性好等特点, 近年来引起了人们的关注. 概括和总结了克酮酸菁染料的结构特点、物化性质及其合成 途径, 同时介绍了它在光学材料、生物和医学等领域潜在的应用价值. 关键词 克酮酸菁染料; 结构; 性质; 合成; 应用 Progress in the Studies of Croconium Dyes Zhang, Shouxin Yang, Xiaobing* Wen, Xiaohong Ding, Songtao Wang, Anbang (State Key Laboratory of Nuclear Biological and Chemical Protection for Civilian, Research Institute of Chemical Defense, Beijing 100191) Abstract Croconium dye is an important part in the cyanine family used as organic function dye, which has been attracted extensive attention recently because of its strong and sharp absorption, large molar absorption coefficient and good photo- chemical stability in the near-infrared region. The unique structure, and physical and chemical properties, together with the recent progress in the preparation methods of croconium dyes are reviewed. The promising application in the fields of optical materials, biology, medicine, etc. is also introduced. Keywords croconium dye; structure; property; synthesis; application 近年来, 有机功能染料引起了人们的极大关注. 有 的次甲基被相应的克酮酸取代而成[8]. 克酮酸菁染料分 机功能染料在光学领域应用广泛, 如光数据存储、光学 子一般由推电子-拉电子-推电子(D-A-D)基团构成, 中 转换和太阳能电池等方面, 同时在荧光检测、抗癌剂、 心的克酮酸是强吸电子基团, 它与两端连接的供电子基 生物分子标记等生物和医学方面也有着广泛的应用. 克