受限介质中光化学反应的研究有机化学.pdfVIP

2006 年第 26 卷 有 机 化 学 Vol. 26, 2006 第 5 期, 599～609 Chinese Journal of Organic Chemistry No. 5, 599～609 ·综述与进展· 受限介质中光化学反应的研究 a a a a b 吕锋锋 吴骊珠*, 张丽萍 佟振合*, 郑利强 (a 中国科学院理化技术研究所 北京 100080) (b 山东大学胶体与界面化学教育部重点实验室 济 250100 ）) 摘要 提高化学反应的选择性始终是化学家关注的热点. 本工作以光 Fries 重排反应、Norrish/Yang 光环化反应、9-取 代蒽衍生物的光二聚反应以及不对称光化学反应为例, 结合近年来在受限介质中光化学反应研究的最新进展, 总结了 利用受限介质控制化学反应选择性的一般规律. 关键词 受限介质; 光反应; 选择性 Recent Advances of Photochemical Reactions within the Confined Media a a a a b LÜ, Feng-Feng WU, Li-Zhu*, ZHANG, Li-Ping TUNG, Chen-Ho*, ZHENG, Li-Qiang (a Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101) (b Key Laboratory of Colloid and Interface Chemistry, Ministry of Education , Shandong Unuversity, Jinan 250100) Abstract The selectivity of the photochemical reactions is always an important concern of chemists. Herein the progress of photochemical reactions, including photo-fries rearrangements, Norrish/Yang photo- cyclization, dimerization of 9-substituted anthracenes and asymmetric photoreactions within the confined media is reviewed and the general rules are summarized for microreactor-controlled selectivity of the pho- tochemical transformations. Keywords confined media; photoreaction; selectivity 以洁净、节能和节约为目标的光化学反应是迅速