含脱氢松香骨架的1,8-萘酰亚胺衍生物的合成及其对阴离子的识别有机化学.pdfVIP

2011 年第 31 卷 有 机 化 学 Vol. 31, 2011 第 2 期, 197～202 Chinese Journal of Organic Chemistry No. 2, 197～202 ·研究论文· 含脱氢松香骨架的 1,8-萘酰亚胺衍生物的合成及其对阴离子的识别 张 业 a,b 冯少波 a 潘英明 a 义祥辉 b 王恒山*,a (a 广西师范大学化学化工学院 桂林 541004) (b 桂林师范高等专科学校化学与工程技术系 桂林 541001) 1 摘要 以歧化松香胺为原料合成了 6 个新型含脱氢松香骨架的 1,8-萘酰亚胺衍生物 2a～2b 和 3a～3d, 其结构用 H NMR, 13C NMR, MS 和元素分析进行了表征. 对 3a～3d 进行了阴离子识别研究, 并对其识别机理进行了讨论. 关键词 1,8-萘酰亚胺; 脱氢松香; 合成; 结构表征; 阴离子识别 Synthesis of Some Novel 1,8-Naphthalimides Bearing Dehydroabietyl Rosin Skeleton and Their Anion Recognition Zhang, Yea,b Feng, Shaoboa Pan, Yingminga Yi, Xianghuib Wang, Hengshan*,a (a College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004) (b Department of Chemistry and Engineering Technology, Guilin Normal College, Guilin 541001) Abstract Some novel 1,8-naphthalimide derivatives bearing dehydroabietyl rosin skeleton were synthe- 1 13 sized from dehydroabietylamine. The title compounds were characterized by H NMR, C NMR, MS tech- niques and elemental analysis. The abilities of anion recognition by these 1,8-naphthalimide derivatives had been investigated. Then the mechanism of anion recognition of such 1,8-naphthalimides was discussed. Keywords 1,8-naphthalimide; dehydroabietyl rosin; synthesis; characterization; recognition of anion 具有光学信息响应功能的主客体分子间的相互作