基于咔唑衍生物的受体化合物对阴离子的识别与传感研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201307016 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 基于咔唑衍生物的受体化合物对阴离子的识别与传感研究进展 刘 勇 张 峰 邹林波 蹇军友 鲍小平* (贵州大学精细化工研究开发中心 教育部绿色农药与农业生物工程重点实验室 贵阳 550025) 摘要 咔唑及其衍生物是一类重要的含氮杂环化合物, 其分子具有较大的共轭体系和刚性结构, 并容易在其骨架上引 入不同基团进行化学修饰. 此外, 咔唑类化合物具有良好的荧光性能, 其分子内所含的NH 单元本身即可作为一个阴离 子识别位点. 总结了近年来咔唑类阴离子受体的研究进展, 按受体分子的几何结构将其分为线型、钳形、环状、枝状、 三足型、寡聚物和聚合物等, 最后对该类受体的发展前景作了展望. 关键词 咔唑; 阴离子受体; 识别; 传感 Recent Progress in Receptor Compounds Based on Carbazole Derivatives for Anion Recognition and Sensing Liu, Yong Zhang, Feng Zou, Linbo Jian, Junyou Bao, Xiaoping* (Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Center for Research and Devel- opment of Fine Chemicals, Guizhou University, Guiyang 550025) Abstract Carbazole and its derivatives are one kind of important nitrogen-containing heterocyclic compounds with a large conjugated system and a rigid structure, and it is easy to introduce different groups into the carbazole backbone. Carbazole compounds have a good fluorescent property, and its NH unit itself can work as one recognition site for anions. In this paper, the recent progress of carbazole-based anion receptors is summarized according to the different geometrical structures of re- ceptor compounds, such as linear, cleft-shaped, cyclic, branched, tripodal, oligomer, polymer etc. The developing prospects of this kind of anion receptors are also discussed. Keywords carbazole; anion receptor; recognition; sensing 设计并合成对特定阴离子具有高亲和性和高选择 unit)和信号单元(signaling unit)组成, 这两部分