甲烷和二氯甲烷混合反应气体的负离子化学电离质谱研究有机化学.pdfVIP

ρ 晶 T 1985 年 254 有机化 CRYSTAL STRUCTURE AND ABSOLUTE CONFIGURATION OF ( + )-IPALBIDINE HYDROBROMIDE MONOHYDRATE Fan Zhaochang Lu Renrong Lao Xiafei Liu Zhujin (Shanghai Institute 01 Organic Chcn: istry, Academia Sinica) Abstract: (+ )-Ipalbidine has been isolated from the chinese medicinal plant Hua Tuo Dou (lpomoea hardwickii Hems l.) and the crystal of (+ )-ipalbidine hydrobromide monohydrate was found tobelong to orthorhombic system with space group P212121 The unit cell paramatersα= 10.078(2)λ ， b=17.303(3) λ ， c=9.022 (1) λ ， z = 4. The inten- sity data were obtained with a four-circle diffractometer and the number of the independ- ent reflections amounted to 1248. The structure was solved by heavy-atom technique and refined by block -diagonal matrix least-squares method. The final R is O. 051. By means of anomalous dispersion of Br , the absolute configuration of the cation was found to be sinister, titled S-I ,2 , 3 , 5 , 8, 9-hexahydro-6-p-hydrooxyphenyl-7-methyl- indolizine. Four molecules in a unit cell were linked in pairs by hydrogen-bonds NH … Br...HOH …OHAr , forming molecular chains running in the b direction. Descriptor: crystal structure, absolute configuration , alkaloid , indolizine (P) , phenol (P). Identifier: ipalbidine. 有机化学， 1985, 3 , 254-260 ORGANIC CHEMISTRY 甲烧和二氯甲烧混合反应气体的负商子化学电窝质谱研究 邓炎 彭荣坤 (中国抖学院上海有机化学研究所〉 摘事a 甲挠和二氧甲:境混合反应气体的负离子化学电离民谱，对多肤和核苦等极性有机化合物的