王冠高聚物担载四核钴羰基族催化剂的醛化反应活性有机化学.pdfVIP

~2 用 ]!)811f: 4 月 了f fn 11-: 户? N2 2 , Apr. , 1!l8.1 黯嚣 王冠高聚物担载四核钻擞基簇催化剂的睦化反应活性 杨佩仪 傅宏祥 罗玉忠 (中罔科学院兰州化学协商!研究所) 摘要g 本文用二苯并-18-冠-6 户0:;1 黑物作ìtl 中时也.~体，通过化学攻台， ，去)J)(了担j飞的凹核恼波边族1比 化剂Crown-Co ，并对i亥催化剂进行了元素分析、红外光L普及X射线光电子能谐(XPS) 等方向的测试分 4 析1 还考察了不同诅度、不同极性rKjrU及不同类型烯怪对隆化洁性的影响。实验证明，该俗化剂对立链 端位烯烧的隆化ìi.，t生高于均柄的苯主主-四核ttt毅基赞{}H{ζ刘 Ph-Co -]8-王1;升高粱物载体能明 。二末并 4 显改善催化性能。 叙调s 冠醋，簇状化舍物， {~H ~古络合物，搜1i~ 约合物， (ìJ{1仁刘，制备，自主化。 Catalytic Activity of Hydroformylation of TetranucIear- cobalt Carbonyl Cluster Supported on Polymer of Crown Ether Yang Peiyi Fu Hongxiang Luo Yuzhong (Laηzhou Institute 01 Chemical Physics , Academiα Sinica) Abstract: Tetranuclear咱obalt carbonyl c1uster , supported on dibenzo-18-crown-6 polymer (Crown-C04 ) was synthesized , and characterized by infrared spectroscopy. elemental analysis and XPs. The effect of temperature. solvents and alkenes upon the catalytic hydroformylation activity was investigated. The experimental results showed that the activity of Crown-Co , catalyst for terminal olefins is higher than that of the homogeneous phenyl-tetranuclear-cobalt carbonyl c1uster catalyst(Ph-Co.). The improve- ment of catalytic activity by DB-18-C-6 polymer was evident. Descriptor: crown ether compound , cluster compound , support. cobalt complex. carbonyl complex. catalyst , preparation. hydroformylation. 枉!载的金属族由于兼具均相及多相催化剂 活性的四核t~Î金属簇，化学馄什?E二苯:Ff:-18-