Surface segregation of copper in antibacterial ferritic stainless steel.pdfVIP

Surface segregation of copper in antibacterial ferritic stainless steel.pdf

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维普资讯 BaosteeiTechnicaiResearch Stainlesssteel Volume2,Number2,June2008,Page55 Surfacesegregationofcopperinantibacterialferriticstainlesssteel ZhangZhixia,LinGangandJiangLai~u TechnologyCenterforStainlessStee1.BaosteelResearch Institute,Baoshan IronSteelCo.,Ltd.,Shanghai200431,China Abstract:Byusingaugerelectronspectroscopy (AES)anddiffusiontheorytonaalyzethesurfacesegregationof copperin na tibacterialferritic stainlesssteel,establishing a diffusion model,na d calculating theactivation energy of diffusionofthecopperinferrite,theaffectofsurfacesegregationonthena tibacterialcapabilitieswereresearched.The resut·ss w thattheconcentration or山ec。ppersuraceat973 K and 昕 3 K cou·d beex essed asn = 。 (一△口+3△尺口+△ ,withthepraametersrelatingtotheconcentrationofthediffusionlayer,thecoefficient ofdiffusion,thelengthofdiffusion,thelatentheatofevaporationnadthelatentheatoffusion.Theactivationenergyof diffusionofcopperinferriteisapproximately221.688kJ/mo1.Thena tibacterialpropertyofthesteelisimprovedasthe surfacesegregationofthecopperisincreased.At1073K for60min,theconcentrationofthesurfacecopperisover threetimeshigherthna thebasicconcentration.Thena tibacterialpropertyofthestainlesssteelcna reach approximately 99.9% . Keywords:ferriticna tibacterialstainlesssteel;coppersurface segregation;diffusion;AES Antibacterial ferritic stainless steel that contains quantity ofadded elements,the surface energy,the copperappearedattheendof20 centuryl1-3] . Since surface entropy,and the quantity of other surface ithasthe propertiescontained by normal types of elements. Reserach results usually vary with the stainlesssteeland itisantibacte

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