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Structural and Optical Characterization of Indium Zinc Oxynitride Thin Films.pdf
JournalofMaterialsScienceandEngineeringA4(3)(2014)91·98
… … N
StructuralandOpticalCharacterizationofIndium Zinc
OxynitrideThinFilmS
Jos4JuanOrtegaSigala一,MariaLeticiaP6rezArrieta,HugoTototzintleHuitle,MiguelAngelAguilarFrutis,
CiroFalcony.VictorHugoM 6ndezGarci andJosddeJesfisAraizaIbarra
j.AeademicUnitofPhysics.UAz.Zacateeas.C.P.98060,Mdxico
2.CiAC、 .UAsLP.SanLuisPotosLC.P 7821o.Mdxico
3 CICATA lPN.M6xicoD.F..C P.11500,Mdxieo
4DepartmentofPhysicsCINVESTAv.IPN.MdxicoD.F..CP.07360,M~xico
Received:February13,2014 /Accepted:March08,2014 /Published:March10,2014
Abstract:Indium zincoxynitride(IZON)thinfilmsweredepositedonSi(1O0)substratesbyRFreactivemagnetronspu~eringat
differentsubstratetemperaturetostudytheirstructuralandopticalproperties.A11thefilmsweredepositedinareactiveatmosphereof
nitrogenandargon.Asprecursormaterial,anIZOtarget(1n203一ZnO,90—10wt%)withapurityof99.99%wasused.Thecrystalline
structureofthefilmswasanalyzedbyX—Raydiffractiontechnique(XRD),thedepositedIZONthinfilmswerepracticallyamorphous
withsomepolycrystallinecontentsforthefilmsdepositedat 100。Cand300。C.Therefractiveindexandtheextinctioncoefficienthad
beenobtainedfromSpectralEllipsometry (SE)analysesusingtheClassicalandAdachimodels,bothresultswerequalitativelyand
quantitativelyapproximate.Theseopticalresultswereanalyzedandusedtoproposeroughnessvaluesofthefilmssurface,throughof
anappropriateproposalofthestructureofthefilms.Theroughnessvaluesobtainedfrom opticalmodelswerecomparedwiththe
moprhologicalresultsstudiedbyAtomicForceMicroscopy(AFM),nadtheroughnessvalues,obtainedbydirectandindirectmeasure,
wereconsistentbetweenthem .FheincorporatednitrogenreducedthetypicalcrystallizationofIZO nadfavoredthedepositionof
transparentthinfilmswithvery flat surfaces,theseresultsshowsthattheIZON hasna idealamorphousmaterialforapplicationsas
conductiveoxynitridelayers.
Keywords
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