Study of Cobalt Electrodeposition onto Stainless Steel Using Electrochemical Impedance Spectroscopy (IES).pdfVIP
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Study of Cobalt Electrodeposition onto Stainless Steel Using Electrochemical Impedance Spectroscopy (IES).pdf
JournalofPhysicalScienceandApplication2(10)(2012)409-413
… … N 疆
StudyofCobaltElectrodepoSitionontoStainlessSteel
UsingElectrochemicalImpedanceSpectroscopy(IES)
EricMarsalhaGarcia,TulioM atencio,RozanaZacariasDomingues,LuanaMarsalhaGarcia,Jacqueline
AmandaFigueiredodosSantos,NarjaraRibeiro2,HosaneAparacidaTar6coandVanessadeFreitasCunhaLins。
1.DepartmentofChem~try,FederalUniversityofMinasGeraisLAMPAC.BeloHorizonte—MG221—8686,Brazil
2FederalUniversiytosaoJ0aoDelRei/CampusSeteLagoas.SeteLagoas—MG221—8686,Brazil
3.DepartmentofChemistryEngineering,FederalUniversiytofMinasGerais,BeloHorizonte-MG221-8686,Brazil
Received:March22,2012/Accepted:April19,2012/Published:October15,2012
Abstract:Thispaperdescribesthestudyofcobaltgrowthmechanism obtainedbyelectr0depOsitiOnmethodwithvariationofpH
solution.Theelectrochemicalimpedancespectroscopy(EIS)andscanningelectronicmicroscopy(SEM)resultswerepossible
conclude thatthe cobaltelectrOdeDositedatpH = 5.40 presentedapproximately an areathreetimeslargerthna the cobalt
electrodepOsitedatpH =2.70.Inaddition,thecobaltelectrOdepOsitedatpH =2.70hadavalueofchargetram,;ferresistanceequalto
l51.6f2c·m ‘andthecobaltelectrodeDOsitedatpH :5.40thisvaluecorrespondsto67.4Q c·m.Thisoccursbecausetheincreasedin
micro.porosityincreasethediffusionofelectrolyteoncobalte1ectrodeDOsitseasilythecorrosionprocess.
Keywords:CobaltelectrOdeposition,electrochemicalimpedancespectroscopy
1.Introduction growth(2D)theadsorbedatomstendstodescendto
substrate.Thisresultin forn-iation ofuniforii1films.
The cobalt and cobalt alloys attracts mnay
However,ifadsorbedatomsmigrateintotopofnucleus,
researchers’attention foritsmagnetic and corrosion
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