Study of Cobalt Electrodeposition onto Stainless Steel Using Electrochemical Impedance Spectroscopy (IES).pdfVIP

Study of Cobalt Electrodeposition onto Stainless Steel Using Electrochemical Impedance Spectroscopy (IES).pdf

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Study of Cobalt Electrodeposition onto Stainless Steel Using Electrochemical Impedance Spectroscopy (IES).pdf

JournalofPhysicalScienceandApplication2(10)(2012)409-413 … … N 疆 StudyofCobaltElectrodepoSitionontoStainlessSteel UsingElectrochemicalImpedanceSpectroscopy(IES) EricMarsalhaGarcia,TulioM atencio,RozanaZacariasDomingues,LuanaMarsalhaGarcia,Jacqueline AmandaFigueiredodosSantos,NarjaraRibeiro2,HosaneAparacidaTar6coandVanessadeFreitasCunhaLins。 1.DepartmentofChem~try,FederalUniversityofMinasGeraisLAMPAC.BeloHorizonte—MG221—8686,Brazil 2FederalUniversiytosaoJ0aoDelRei/CampusSeteLagoas.SeteLagoas—MG221—8686,Brazil 3.DepartmentofChemistryEngineering,FederalUniversiytofMinasGerais,BeloHorizonte-MG221-8686,Brazil Received:March22,2012/Accepted:April19,2012/Published:October15,2012 Abstract:Thispaperdescribesthestudyofcobaltgrowthmechanism obtainedbyelectr0depOsitiOnmethodwithvariationofpH solution.Theelectrochemicalimpedancespectroscopy(EIS)andscanningelectronicmicroscopy(SEM)resultswerepossible conclude thatthe cobaltelectrOdeDositedatpH = 5.40 presentedapproximately an areathreetimeslargerthna the cobalt electrodepOsitedatpH =2.70.Inaddition,thecobaltelectrOdepOsitedatpH =2.70hadavalueofchargetram,;ferresistanceequalto l51.6f2c·m ‘andthecobaltelectrodeDOsitedatpH :5.40thisvaluecorrespondsto67.4Q c·m.Thisoccursbecausetheincreasedin micro.porosityincreasethediffusionofelectrolyteoncobalte1ectrodeDOsitseasilythecorrosionprocess. Keywords:CobaltelectrOdeposition,electrochemicalimpedancespectroscopy 1.Introduction growth(2D)theadsorbedatomstendstodescendto substrate.Thisresultin forn-iation ofuniforii1films. The cobalt and cobalt alloys attracts mnay However,ifadsorbedatomsmigrateintotopofnucleus, researchers’attention foritsmagnetic and corrosion

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