NO_SO2对纳米氧化铁脱除单质汞性能的影响.pdfVIP

第 30 卷 第 35 期 中 国 电 机 工 程 学 报 Vol.30 No.35 Dec.15, 2010 2010 年 12 月 15 日 Proceedings of the CSEE ©2010 Chin.Soc.for Elec.Eng. 43 0258-8013 (2010) 35-0043-06 O 643 A 470 10 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ NO/SO 对纳米氧化铁脱除单质汞性能的影响 2 孔凡海，邱建荣，刘豪，赵然，曾汉才 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市 430074) Effect of NO/SO on Elemental Mercury Adsorption by Nano-Fe O 2 2 3 KONG Fanhai, QIU jianrong, LIU Hao, ZHAO Ran, ZENG Hancai (State Key Laboratory of Coal Combustion(Huazhong University of Science and Technology),Wuhan 430074,Hubei Province, China) ABSTRACT: The effect of NO, SO2 on gas-phase Hg0 进入人体。煤燃烧引起的汞排放是大气汞排放的主 adsorption by nano-Fe O was evaluated on a fixed bed reactor 2 3 要来源，若不加控制排入大气将会污染环境，危害 using an online gas-mercury analyzer. The results show that the 人类健康。燃煤烟气中汞以多种形式存在，其中， presence of NO could enhance the Hg0 adsorption by 单质汞具有较高的挥发性和较低的水溶性，是最难 nano-Fe O , the mercury adsorption capacity of nano-Fe O 2 3 2 3 gradually improves as the NO concentration increases, more 控制的形态之一[1-2] 。 than 96% of total mercury is removed when 200×10-6 NO is 采用吸附剂(碳基、钙基、飞灰等)脱除燃煤烟 introduced. The inhibiting effect of SO2 on Hg0 capture was 气中的汞是一种有效的脱汞方式，而寻求经济性 0 detected as it could compete with Hg for adsorption sites. In 好、吸附容量大以及产物易处理的多功能吸附剂对 the NO/SO2 condition, the adsorption efficiency and the