可控性电化学振荡和其在三维有序阵列结构制备中的应用.pdfVIP

Journal of The Electrochemical Society, 162 (9) E129-E133 (2015) E129 0013-4651/2015/162(9)/E129/5/$33.00 © The Electrochemical Society Tunable Electrochemical Oscillation and Regular 3D Nanopore Arrays of InP Xiangyu Chai,a Zhankun Weng,a,z Liping Xu,a and Zuobin Wanga,b a CNM JR3CN, Changchun University of Science and Technology, Changchun 130022, People’s Republic of China bJR3CN IARC, University of Bedfordshire, Luton LU1 3JU, United Kingdom Tunable potential oscillations are obtained by electrochemical etching of n-InP (100) in the 3 M NaCl solution using the chronopten- tiometry with current ramp. The regular 3D nanopore arrays are formed with the change of the current density from 320 to 260 mA · cm−2 at the scan rate 0.72 - 0.80 mA · cm−2 · s−1. The results showed that the current density ranges and scan rate have the effect on the E-t curves and the pore’s morphology. The scan rate can regulate not only on the charge consumed per period but also on the amplitude of potential oscillation, and shown that the charge per period and the amplitude can be tuned when proper electrochemical parameters are selected. Furthermore, the pore’s morphology will change from the regular structure to irregular with the increasing of the scan rate. In addition, the relation has also been discussed between the E-t curves and the pore’s morphology. © 2015 The Electrochemical Society. [DOI: 10.1149/2.0341509jes] All rights reserved.