温度对麦秆湿解产物特性的影响.pdfVIP

第 34 卷 第 26 期 中 国 电 机 工 程 学 报 Vol.34 No.26 Sep.15, 2014 4508 2014 年 9 月 15 日 Proceedings of the CSEE ©2014 Chin.Soc.for Elec.Eng. DOI ：10.13334/j.0258-8013.pcsee.2014.26.009 文章编号：0258-8013 (2014) 26-4508-07 中图分类号：TK 6 温度对麦秆湿解产物特性的影响 郭淑青，刘开拓，董向元 ( 中原工学院，河南省 郑州市 450007) Influence of Temperature on Product Characteristics Associated With the Hydrothermal Treatments of Wheat-Straw GUO Shuqing, LIU Kaituo, DONG Xiangyuan (Zhongyuan University of Technology, Zhengzhou 450007, Henan Province, China) ABSTRACT: Hydrothermal treatment is a thermochemical 220 ℃以后，变化速度加快，如以生产固体生物炭为主，温 conversation process to simulate natural coalification. To 度应控制在 220 ℃左右。固体产物中有机官能团随温度的升 investigate the physic-chemical characteristics of products 高而减少，而碳碳双键、羰基和难降解的芳环结构，随温度 from biomass hydrothermal treatments, the hydrothermal 的升高，红外吸收加强；固体表面的孔隙和微球显示其具有 experiments were performed using wheat straw as feedstocks 生物炭的结构；200 ℃的固体产物展现出相对较好的热稳定 in a pressure reactor at various temperatures (160~240 ℃) in 性。液体产物中含有还原性糖、乙酸、糠醛、5-羟甲基糠醛 period of 60 min. The results show that with the temperature 和 5- 甲基糠醛，其中还原性糖浓度较高，可以作为液体燃 increasing, the solid production rate decreases gradually, and 料的原料，随温度的升高，还原糖浓度逐渐增加，200 ℃后， the liquid production rate increases. Moreover, the changes are 浓度变化不大。 remarkable above 220 ℃.The operating temperature should be 关键词：湿解；温度；麦秆；物化结构；浓度分布 controlled at about 220 ℃ when the hydrothermal reaction is mainly for producing solid biochar. The organic functional 0 引言 groups of soli