烧结对钙基吸收剂循环煅烧_碳酸化捕集CO2影响.pdfVIP

第34 卷 第35 期 中 国 电 机 工 程 学 报 Vol.34 No.35 Dec.15, 2014 2014 年12 月15 日 Proceedings of the CSEE ©2014 Chin.Soc.for Elec.Eng. 6271 DOI ：10.13334/j.0258-8013.pcsee.2014.35.003 文章编号：0258-8013 (2014) 35-6271-08 中图分类号： TQ 424 烧结对钙基吸收剂循环煅烧/碳酸化捕集 CO 影响 2 王春波，周兴，张斌，白彦飞 (华北电力大学能源动力与机械工程学院，河北省 保定市 071003) Effect of Sintering on the Limestone Calcination/Carbonation Looping Cycle for CO Capture 2 WANG Chunbo, ZHOU Xing, ZHANG Bin, BAI Yanfei (School of Energy and Power Engineering, North China Electric Power University, Baoding 071003, Hebei Province, China) ABSTRACT: A customized experimental system that can 关键词：钙基吸收剂；循环煅烧/碳酸化；烧结；水蒸气； measure sample weight at constant temperature was used to test 孔结构 the factors (time, steam, temperature, particle size, etc.) that 0 引言 could affect sorbent sintering. And, the pore structure was measured. It shows both carbonation rate and final ratio of CO2 是主要的温室气体，其减排越来越受到人 sorbent decrease with sintering duration, especially during the 们的关注。煤燃烧是最大的CO2 单点排放源。世界 chemical reaction stage. Steam play has different roles for 3 范围内，燃煤电厂排放的 CO2 约占其总排放量的 tested influence of different sintering duration of CaO. The 33%~40% ，我国甚至高达 73%[1] 。在现有的 CO2 sintering of CaO is accelerated by higher temperature and that 捕集技术中，钙基吸收剂循环煅烧/碳酸化法由于吸 leads to less carbonation ratio of CaO. The highest carbonation 收剂分布广泛、价格低廉，被认为是较有前景的捕 ratio is got