复合污染土壤中Hg的形态和无机离子对其释放能力的影响研究.pdfVIP

安徽农业科学，JournalofAnhui 责任编辑姜丽责任校对王淼 Agri．Sci．2007，35(35)：11517—11518，11521 复合污染土壤中Hg的形态及无机离子对其释放能力的影响研究 李杰颖1，梁成华2，刘方H，杜立宇2姚敏z，张宇2 (1．贵州大学生命科学学院，贵州贵阳550025；2．沈阳农业大学土地与环境学院，辽宁沈阳110161) 摘要f目的1为污染土壤的控制和修复治理提供科学依据。f方法1以沈阳某冶炼厂废旧厂区土壤为研究对象，采用连续浸提一形态分 析法对汞形态进行分析，并以几种无机盐离子作浸提剂，研究不同离子浓度对污染土壤中汞的释放情况。『结果1土壤样品中汞主要以 残渣态或晶格态存在，占87．40％，其次是难氧化降解有机质及某些硫化物结合态。随着S0。。和cl一浓度的增加，汞的释放量逐渐增 或晶格态存在。不同阴离子在不同的浓度范围内对Hg的释放能力不同。强酸条件能大大增强汞的溶出毒性。 关键词复合污染土壤；汞；形态；释放 中图分类号 S151．9文献标识码A 文章编号0517—661l(2007)35—11517—02 onVarious andTheirRelease Ionin SoilPollution MercurySpecies byInorganicCompound Investigation LI et ofLifeScience，Guizhou 550025) Jie-yingal(College University，Guiyang．Guizhou this to for andtreatmentofsoil AbstraetfObieetiveltheaimof scientificbaseeontrolandremediation With studyprovide pollution．『Methodl thesoil fromthea smelt in astestedsoilthesoil were sampled deposedfactorysregionShenyang mercuryspeciesanalyzedbysequentiM severalfamiliar saltionsas the releasefromthecontaminatedsoil theiOnS extractionmethod．With mercury species jnorganic extractingagent by witlldifferentconcentrationwas inthesoil existedinformofresidueor lattice for studied．fResultlMercury samples crystal 87．40％．followed oxidationand matterandsomebound—statesulfide．The amount byhardlydegraded degradationorganic mercuryreleasing enhancedwiththeinerementofS(3ld2-and over50mmol／Lincreasedthe on withits most C1一．co?一at releasingabilityHg weakinthe on amountinthe