β-羧基丙酸羟丙基甲基纤维素酯(β-CPHPMC)制备特性研究分析.docVIP

β-羧基丙酸羟丙基甲基纤维素酯(β-CPHPMC)的制备与 沈纪洋 天津大学 材料科学与工程学院， 天津市 300072 摘要 本文HPMC）为原料、丁二酸酐为酯化剂、无水醋酸钠为催化剂在醋酸中通过改变温度、酯化剂和催化剂的用量制备了五种具有不同β-羧基丙酰基含量β-羧基丙酸羟丙基甲基纤维素酯(β-CPHPMC)。结果表明：β-羧基丙酰基含量越多，分布越均匀，β-CPHPMC凝胶温度越低℃，而相同浓度的HPMC的凝胶温度为59.85℃。 关键词：β-羧基丙酸羟丙基甲基纤维素酯 羟丙基甲基纤维素 丁二酸酐 β-羧基丙酰基 凝胶温度Preparation and Characterization of β-carboxypropionate Hydroxypropylmethyl Cellulose (β-CPHPMC) SHEN Ji-yang (School of Material Science and Engineering, Tianjin University, Tianjin 300072, China) Abstract β-carboxypropionate hydroxypropylmethyl cellulose (β-CPHPMC) was synthesized from hydroxypropylmethyl cellulose (HPMC) by esterification using succinic anhydride as esterifying agent, anhydrous sodium acetate as catalyst and acetic acid as organic solvent. By varying reaction temperature and the amount of esterifying agent and catalyst, five kinds of β-CPHPMCs with the different content of β-carboxypropionyl groups were prepared. The content of β-carboxypropionyl groups in β-CPHPMC was determined by conductometric titration at a constant temperature of 29℃. The structure and properties of β-CPHPMC were analyzed by IR, viscometer and rheometer. The result showed that the number of β-carboxypropionyl groups per cellulosic macromolecular chain was from 6.57 to12.42, that the gelation temperature of 1wt％ β-CPHPMC solution ranged from 48.7℃ to 41.95℃, whereas that of a 1 wt% HPMC solution was 59.85℃ and that with an increase in β-carboxypropionyl content and distribution homogeneity, the gelation temperature of β-CPHPMC decreased but its gel strength increased. Key words: β-carboxypropionate hydroxypropylmethyl cellulose; succinic anhydride; hydroxypropylmethyl cellulose; β-carboxypropionyl group; gelation temperature; gel strength 作者简介：沈纪洋（1981－），男，硕士生，从事纤维素醚的化学改性研究，电话E-mail:sjyzmh@163.com 源于天然资源的纤维素衍生物羟丙基甲基纤维素HPMC在食行业中已得到广泛使用，如可用来提高无谷蛋白面包的结构和松软性，也可用于使用的涂膜材料。但近年来，其热可逆凝胶性质逐渐成为研究热点。水溶液形成凝胶的主要驱动力是对温度非常敏感的分子间或链段间的缔合或组装。这种缔合是由于分子链中的疏水基团所致，而羟丙基的存在对凝胶强度，特别是凝胶温度影响非常大。在低温下，完全水化，水分子在疏水基团周围形成类似冰结构随