超临界二氧化碳预处理促进稻杆水解制备还原糖研究.pdfVIP

第九届全国超临界流体技术学术及应用研讨会论文集 超临界二氧化碳预处理促进稻杆水解制备 还原糖研究 * 罗鹏 王恩俊 徐刚 刘一凡 银建中 大连理工大学化工机械学院，辽宁省 大连市，116024 生物质水解可制备还原糖。本文以稻杆为原料，使用超临界CO2 预处理之后再用稀酸水解对预处理效果进 行评价。重点考察了预处理温度、原料含水量对还原糖产率的影响。结果表明，稻杆超临界 CO2 预处理的最佳 条件为：100℃，含水量 50%，30min，15MPa；稀酸水解条件为：140℃，40min，液固比 50:1，质量分数 1% 硫酸催化剂。所得最大还原糖产率为 36.6%，相比空白样提高了5.7%。扫描电镜（SEM）表征发现，稻杆预处 理之后表面粗糙度增大，有利于水解；经高效液相色谱（HPLC ）对预处理前后的还原糖成分进行分析，发现 预处理对纤维素的水解有一定的提升效果。 关键词：稻杆；预处理；超临界二氧化碳；水解；还原糖 Increasing Yield of Reducing Sugars from Rice Straw Hydrolysis by Supercritical Carbon-dioxide Pretreatment LUO Peng, Wang En-jun, Xu Gang, LIU Yi-fan, YIN Jian-zhong* School of Chemical Machinery, Dalian University of Technology; Dalian 116023; China Reducing sugars can be derived from biomass hydrolysis. The rice straw hydrolysis was conducted at 140 ℃ and the hydrolysis time is 40min; the liquid-solid ratio was 50:1 with 1% mass fraction sulfuric acid catalyst after supercritical carbon dioxide pretreatment. The effects of pretreatment temperature and moisture content on the yield of the reducing sugars were emphasized. As the result shows, the optimum conditions of rice straw supercritical carbon dioxide pretreatment were 100℃, 50% moisture content, 30 min, 15 MPa. The highest yield of reducing sugars is 36.6% and it is increased by 5.7% compared with the control sample. SEM analysis indicates that the surface roughness of the rice straw was increased which is beneficial to the hydrolysis; the composition of the reducing sugar was confirmed by HPLC analysis and the result demonstrates that supercritical carbon dioxide pretreatment can improve the reducing sugars to some extent. Key words：Rice