环境中多环芳烃的监测和结构表征分析.pptx

;;;;;;;;;;;;;;;;;;; pre-treatment of PAHs;Common detection method of PAHs; GC-FID has?the characteristics of high selectivity, high resolution and high sensitivity . But ,it can’t measure low volatility of PAHs well.;New ?detection method of PAHs; UPLC has small?size?filler and high-pressure pump . UPLC-MS is well used in simultaneous determinating benzo[a]pyrene and eight of its metabolites [8].;Structural characteristics of PAHs;conclusion; references? ;[6]?Riahi K., Sellier N. Separation of isomeric polycyclic aromatic hydrocarbons by GC-MS: differentiation between isomers by positive chemical ionization with ammonia and dimethyl ether as reagent gases. Chromatographia, 1998, 47(5/6): 309-312 [7] Boden A. R., Ladwig G. E., Reiner E. J. Analysis of polycyclic aromatic compounds using microbore columns. Polycycl Aromat Compd, 2002, 22: 301-310 [8] Zhua S., Li L., Thornton C., Carvalho P., Avery B. A., Willett K. L. Simultaneous determination of benzo[a]pyrene and eight of its metabolites in Fundulus heteroclitus bile using ultra-performance liquid chromatography with mass spectrometry. J. Chromatogr. B, 2008, 863: 141-149 [9]?Ong R., Lundstedt S., Haglund P., Marriott P. Pressurised liquid extraction-comprehensive two-dimensional gas chromatography for fast-screening of polycyclic aromatic hydrocarbons in soil. J. Chromatogr. A, 2003, 1019: 221- 232 ;