Theinterfaceofademixedcolloidpolymermixture精品课件.pptVIP

Interfacial tension Life at ultralow interfacial tension: The interface of a demixed colloid-polymer mixture Henk Lekkerkerker Definition of a Colloid Colloids as Atoms Ann. d. Physik, 17, 549 (1905) Why Interesting? Dynamics Outline Phase separation and Interface formation Interfacial profile at a wall Thermal capillary waves Droplet Coalescence Rigid spheres moving through the interface System Experimental setup: Laser Scanning Confocal Microscopy Stage 1: Spinodal decomposition Coarsening rate due to capillary flow Stage 3 Gravity driven flow Stage 4 Interface formation Outline Phase separation and Interface formation Interfacial profile at a wall Thermal capillary waves Droplet Coalescence Rigid spheres moving through the interface Interface at a wall Pressure balance Interface profile Outline Phase separation and Interface formation Interfacial profile at a wall Thermal capillary waves Droplet Coalescence Rigid spheres moving through the interface Interface roughness Thermal capillary waves System Free interface Towards critical point Height distributions Interface localization Static correlation function Interfacial tension Capillary length Dynamic correlation function Interfacial tension Capillary time Outline Droplet Coalescence Droplet coalescence I. Film drainage Drop shape II. Film rupture III. Growth of the neck IV. Spreading into the bulk phase Outline Phase separation and Interface formation Interfacial profile at a wall Thermal capillary waves Droplet Coalescence Rigid spheres moving through the interface Stages of sphere breakthrough Droplet vs. Sphere drainage Droplets Spheres Droplet vs. Sphere drainage II. Connection III. Pull by wetting (1) III. Pull by wetting (2) IV. Detachment Summary and Outlook Life at ultralow interfacial tension is life at low Reynolds number life with thermal fluctuations Microfluidics:Fluid physics at the nanoliter scale How far can we go? Thermal fluctuations will set the limits Droplet b