银纳米线的自组装合成.pptVIP

The Self-Assemble Synthesis of Ag Nanowires 蒋莉 谷穗 易娜 程若霖 宛刚 邓健 陆翔 张云龙 Introduction Self-assemble Ag Nanowires by Polyol Process Three-Phase-Interface Self-Assembly Process Conclusion Content 1、Transparent conductive electrode （a promising substitute of ITO films） 2、As a substrate for Surface enhanced Raman scattering 3、Unique template for novel nanostructures and functional nanomaterials （Yugang Sun,Nanoscale, 2010, 2, 1626–1642） Properties of Ag nanowire Approaches for the Production ofAg Nanowires “hard” templates:These templates were effective in fabricating nanowires with uniform and controllable dimensions, many of them needed to be selectively dissolved under harsh conditions in order to harvest the nanowires. “soft” templates: The silver nanowires synthesized using these templates were often in the form of aggregated bundles, and the templates also needed to be removed in order to recover the individual nanowires. Templateless (avoid the step of template removal) : The products of these templateless methods were, however, often characterized by problems such as relatively low yields, irregular morphologies, polycrystallinity, and low aspect ratios. Polyol Processes 1000 Self-assemble Ag Nanowires by Polyol Process EG: solvents and reductants (Ethylene glycol) Pt Seeds : nuclei for the epitaxial growth of silver. PVP: polymeric surfactants. AgNO3: Ag sources, while nitrates are uncertain. Main Chemicals and Their Roles Yugang Sun,Yadong Yin,Brian T, Mayers,Thurston Herricks, Younan Xia. Chem. Mater. 2002, 14, 4736-4745 Diameter: 30-40nm Lengths: ～50μm With FCC phase Schematic Illustration of The Process Results of TEM image and XRD patterns Nitrate Ion ——Growth Mechanism for Ag nanowires (a) AgClO4 (b)AgNO3 Chien Lin Kuo and Kuo Chu Hwang. Langmuir. 2012, 28, 3722?3729 Other anions, such as ClO4?, B2O72?, NO2?,CO32?, HPO42?, SO42-, only Ag nanoparticles were formed. N