《Literature Reports》.ppt

Reporter：huangyanhua Date:2015.12.07 Email:949945280@ Literature Reports 东华理工大学化学生物与材料科学学院 Faculty of Biology, Chemistry and Material Science, East China Institute of Technology content Background 1 Experiment 2 Results and Discussions 3 Conclusion 4 background There are some defects in the existing methods for uranium detection,such as mercury containing electrodes. so the electrochemical scientists studied a new type of electrode ,which is today I want to talk about the PAA/GRA electrode experimental 1 Experimental Reagents PAA DDW Boric acid 2 Device PGSTAT12 Spectroscopic graphite rods Platinum wire 3 Preparation of modified electrode 4 Sample preparation 5 Experimental process Results and dicussions Fig. 1. Tentative view of the interaction of U(VI) ions with the immobilized 6-O-palmitoyl-l-ascorbic. Fig. 2. Effect of the concentration of PAA on the performance of the sensors.13.5 g L?1 of U(VI); Preconcentration step, 0.1 M H3BO3, pH 4.3, 10 min; measurement step, 0.1 M H3BO3, pH 3.4; DPV parameters: modulation amplitude, 80 mV;modulation time, 30 ms; interval time, 150 ms. Fig. 3. Effect of the pH of the stripping solution on the voltammetric peak of uranium at the two-step procedure. Conditions as in Fig. 2. Fig. 4. Response of the GRA/PAA sensors to different concentrations of U(VI). The inset graph illustrates the respective calibration curve. Conditions as in Fig. 2. Fig. 5. Response of GRA/PAA sensors to various ions. Conditions as in Fig. 2. Fig. 6. Recovery of uranium at a lake water sample and at an acidified lake water sample treated in a C-18 microcolumn. Conditions as in Fig. 2.