《Novel sensitive electrochemical sensor for determination of epinephrine based on a glassy carbon electrode modified with GraphenePoly-brilliant cresyl blue nanocomposites》.ppt

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《Novel sensitive electrochemical sensor for determination of epinephrine based on a glassy carbon electrode modified with GraphenePoly-brilliant cresyl blue nanocomposites》.ppt

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Novel sensitive electrochemical sensor fordetermination of epinephrine based on a glassy carbon electrode modified with Graphene/Poly-brilliant cresyl blue nanocomposites Reporter： Cindy Date：2015.1.5 Content Background 1 Experiment methods 2 Result and Disscussion 3 1 Background 肾上腺素(EP)：肾上腺释放的一种激素、神经传送体拯救濒死人类或动物必备品临床应用：过敏性休克、心搏骤停的抢救过敏性疾病（支气管哮喘、荨麻疹）的治疗灿烂甲酚蓝(BCB) 石墨烯(Graphene) 2 Experiment methods 滴涂法二步法电聚合 Graphene/PBCB/GCE 3 Results and Discussions 引发和聚合 Fig.1 The initiation view of the BCB with two-step electropolymerization Inset: The polymerization view of the BCB 1 Characterization of the modified electrode Fig. 2 Typical SEM images of (a) Graphene/GCE, (b) PBCB/GCE, (c) Graphene/PBCB/GCE SEM Fig.3 EIS of the (a) bare GCE, (b) PBCB/GCE, (c) Graphene/GCE and (d) Graphene/PBCB/GCE in 10mM K3[Fe(CN)6]/K4[Fe(CN)6] (1:1) mixture with 0.2M KNO3. EIS Fig.4 Cyclic voltammograms of K3[Fe(CN)6](1mM) recorded on (a) bare GCE, (b) Graphene/GCE, (c) PBCB/GCE, (d) Graphene/PBCB/GCE in KNO3(0.2M). CV 2 Electrochemistry of the Graphene/PBCB/GCE Fig.5 CV of Graphene/PBCB/GCE in 0.1M PBS (pH 7.0) at various scan rate: The word a-i correspond to 5,10,20,50,100,200,300,400 and 500mVs-1. A: The linear dependence of peak currents (Ip) with scan rates. B: The linear dependence of peak potential (Ep) with the logarithm of the scan rates. C: Magnification of the same plot for high scan rates. Formula Reference (E. Laviron. J Electroanal Chem.1979) Fig.6 CV recorded for Graphene/PBCB/GCE in various pH PBS (containing 100μM EP) separately Inset: Corresponding linear curve of peak potential vs. pH 3 Effect of pH 微电子 Scheme.1. Electrochemical oxidation mechanism of EP 4 Electrocatalytic activity of Graphene/PBCB/GCE to EP determination Fig. 7 CV of Graphene/PBCB/GCE in saturated PBS (pH 7.0) containing various concentration of EP (a) 1, (b)50, (c) 100, (d) 150, (e) 200,(f) 400, (g) 600, (h) 800 and (i) 1000μM EP. Inset ABC shows the lin