A Global Kinetic Mechanism for the Prediction of Hg Oxidation by a Chlorine Species.docVIP

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A Global Kinetic Mechanism for the Prediction of Hg Oxidation by a Chlorine Species.doc

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A Global Kinetic Mechanism for the Prediction of Hg Oxidation by a Chlorine Species.doc

A Global Kinetic Mechanism for the Prediction of Hg Oxidation by a Chlorine Species [a]Foster Wheeler North America Corp., 53 Frontage Road, PO Box 9000, Hampton, NJ 08827, U.S.A. 　　[b]Energy Research Center, Lehigh University, Bethlehem, PA 18015, U.S.A. 　　[c]Centro de Ingenieria y Desarrollo Industrial, Santiago de Querétaro. Qro. 76130 México. 　　[d]Faculty of Mechanical Engineering, Universidad Michoacana de San Nicolás de Hidalgo, Santiago Tapia 403, Col. Centro, CP 58000; Morelia Michoacán, México. 　　*Corresponding author 　　Funding for this experimental work was provided by Foster Wheeler North America Corp. 　　Received 20 June 2012; accepted 10 August 2012 　　Abstract 　　This paper presents a global kinetic model developed from laboratory test results. The model consists of five global reactions -- two reversible and three irreversible. The reaction constants for the Arrhenius expression formulation were determined from a set of 35 experiments involving a variety of flue gas compositions that include bulk gases N2, CO2 and O2 and trace gases NO, SO2, Hg, Cl2 ; at a range of temperatures from 540°C to 166°C and a variety of residence times between 2.7 and 3.3 seconds . The values obtained for the reaction constants were further used to predict experimental data from eleven published mercury data sources. The predicted values corresponded very well compared to the observed published data. 　　Key words: Kinetics model; Mercury emission; Homogeneous mercury oxidation 　　Agarwal, H., Romero, C.E., Rosales, F.H., Mendoza-Covarrubias, C. 2012 . A Global Kinetic Mechanism for the Prediction of Hg Oxidation by a Chlorine Species. Energy Science and Technology, 4 1 ,-0. Available from: URL: /index.php/est/article/view/10.3968/j.est.1座机电话号码0120401.332 　　DOI: /10.3968/j.est.1座机电话号码0120401.332 　　INTRODUCTION 　　The U.S. Environmental Protection Agency EPA submitted a mercury Hg study report to the U.S. Congress in 1997 stating that of the 158 tons of Hg released into