2004 不同活性高岭土矿物聚合反应的研究.docxVIP

第22卷第4期材 料科学与工 程学报总第90期V01．2 2No．4Journal of Materials Science＆EngineeringAug．2004========一=========================================================================================================================一文章编号：1004-793X(2004)04-05踟-04不同活性高岭土矿物聚合反应的研究王鸿灵，李海红，冯治中。田农，阎逢元(中科院兰州化学物理研究所固体润滑国家重点实验室，甘肃兰州730000)【摘要】使用8M氢氧化钠溶液和模数为3．2的硅酸钠水玻璃的混合溶液为激发剂，选用两种不同活性的高岭土在摩温、4MPa的压力条件下制备了矿物聚合物材料。通过XRD、IR和SEM等手段研究了矿物聚合反应的机理，考察_『高岭土的活性对矿物聚合反应的影响，观察了基于高岭土的矿物聚合物材料的形貌。结果表明，较高活性的高岭土在激发剂作用下发，}i_r较完全的矿物聚合反应，其产物可以用XRD得到明显的鉴别，而低活性高岭土与激发剂的作用产物XRl)j：没有明显的特征识别；两种活性高岭土基的矿物聚合反应产物均为层状结构，基于高活性高岭士的矿物聚合反应产物的层的连续性和致密性比基于低活性高岭土的好。【关键词】高岭土；活性：矿物聚合物；矿物聚合反应；激发剂中图分类号：TQl74文献标识码：AStudy of GeopolymerBased on Kaolinite with Different ActivationWANG Hong—ling，LI Hai-hong，FENG Zhi-zhong，TIAN Nong，YANG Feng-yuan(State KeyLaboratoryof SolidLubrication，Lanzhou Insitute of Chemical Physics，ChineseAcademy of Sciences，Lanzhou 730000，China)【Abstract】Kaolinite—basedgeopolymerwassuccessfullysynthesized usingcompoundactivatorcomposedof sodiumsilicatesolutionandsodiumhydroxide solution al room temperature and the pressure of about 4Mpa．Mechanism of geosynthesis was studied by XRD、IR．Shape of geopolymer was observed using SEM．The ef佟ct of activation of kaolinite on geosynthesis was investigated．The result shows thatgeosy vilhesis was occurred when the two kinds of kaolinite were activated by the compound activator．Geopolymer material derived from kaolinile with high degree aetivation can be easily identified by XRD pattern，while that low degree activation kaolinite—based has notconsider‘ahleinfm‘nmtionontheXRDpattern．SEMimagesindicatethegeopolymer based on the two kinds of kaolinite is layer structure．Geopolynlei’nmterialprodu(‘edfromkaolinite withhighdegreeactivationhasbettercontinuityof layer structure and more compact than that ofkaolinile withlowdegreeactivation．【Key words】kaolinile；aeti,。alioll；geopolymer；gcosynthesis；inorganic polymer引言1978年以来．Joseph 1)avidovits开发了矿物聚合物材料 (geol，olymer)”二。矿物聚合(g