高f分子化学总复习.pptVIP

Chapter 5 Ionic polymerization Cationic polymerization is limited to those monomers with electron-releasing substituents such as alkoxy, phenyl, vinyl and 1,1-dialkyl for example, butylene, alkoxy alkene, conjugated alkene Anionic polymerization takes place with monomers possessing electro-withdrawing groups such as nitrile, carboxyl, phenyl, and vinyl 共轭烯烃类单体可进行自由基、阳离子、阴离子聚合 会判断哪些单体能进行自由基、阳离子、阴离子聚合 根据反应条件中给出的引发剂种类即能判断聚合反应是自由基、阳离子或阴离子聚合 Cationic polymerization: Lewis酸　Lewis acid Anionic polymerization: Lewis碱 (alkali metal, metal alkyl) Living anionic polymerization why anioni