g a s- p h a s e a d s o r p t i o n- pomona college（g s - p h s e d s o r p t i o n -波莫纳大学）.doc

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g a s- p h a s e a d s o r p t i o n- pomona college（g s - p h s e d s o r p t i o n -波莫纳大学）.doc

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g a s- p h a s e a d s o r p t i o n- pomona college（g s - p h s e d s o r p t i o n -波莫纳大学）

GAS-PHASE ADSORPTION INTRODUCTION. In this experiment you will study the adsorption of gaseous nitrogen and dimethyl ether on a molecular sieve. Molecular sieves are commonly used as adsorbents and solid supports in chromatography. The mechanism of their mode of action is instructive in understanding the function of catalysts based on zeolites. The procedure is routinely employed in the characterization of catalysts since the adsorption of a substrate on a catalytic surface is the first step in the mechanism of catalysis. The experiment will also introduce you to manipulations on a vacuum line. BASIS FOR THE EXPERIMENTAL PROCEDURE. The apparatus is displayed in Figure 1. Broadly speaking, it consists of a vacuum pump, pressure gauges, a ballast for storing the gas, a sample cell containing the adsorbent, a source of the gas, and a manifold that connects the components. The general approach is quite straightforward. One transfers a known amount of gas to the system and with the aid of a pressure gauge measures the amount of gas adsorbed by the adsorbent. Figure 1. Components of the vacuum line. Key: A, stopcock A; B, stopcock B; ballast, ballast cell connected to the manifold via stopcock C; cell, tube with the adsorbent, connected to the manifold via stopcock D; MKS, MKS Baratron pressure gauge; MKS-C, controller for the MKS gauge; PT50, Leybold PT50 turbomolecular pump system; sample, cylinder of dimethyl ether with a regulator, connected to the manifold via tygon tubing and stopcock E; TC, thermocouple gauge; TC-C, controller for TC. A detailed discussion of the vacuum system is necessary in order to understand the manipulations and the calculations that you will employ to analyze the data. The goal is to determine for a substance the number of moles adsorbed on an adsorbent as a function its partial pressure. One starts at the right with a Leybold PT50 turbomolecular pump system that has two components, a roughing pump and a turbomolecula