Environmental Chemistry The University of Texas at 德克萨斯大学环境化学.pptVIP

下载本文档

0
0
约7.97千字
约 26页
2017-02-13 发布于上海
举报
版权申诉

Environmental Chemistry The University of Texas at 德克萨斯大学环境化学.ppt

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Environmental Chemistry Cautions for a Finite World Topics Natural Cycles Water Oxygen Carbon Nitrogen Energy Anthropogenic Burdens Enviromental Divisions Atmosphere Hydrosphere Biosphere Lithosphere “Better Living through Chemistry” “Solution to Pollution is Dilution” Mantra presumes infinite reservoirs. Treats pollution as a local concentration to be reduced by an ? of natural purity. Need for reduction well below LD50. Diffusion and mass transport aid the myth. Unrelenting contamination overwhelms. All sinks are finite sinks. Equilibrium and kinetics are unforgiving. Kinetics and Thermodynamics In evolving systems, current states are a function of both. Thermodynamics says where equilibrium would lie if it ever arrived. Kinetics declares the rate at which species are evolving in time. Via the rates of chemical reactions Via diffusion and mass transport Degradation in Dilution Model As equilibrium (pollution homogeneity) approaches, sink rates slow. Product “pressures” dictate that reverse reactions (return of contaminants) rise to counter the cleansing protocols. ? dilution is not the answer. Understanding long-range planning are. Global Water Cycle Despite drought and its famine … Water’s global cycle is little altered by us. Solar evaporation ? humid atmosphere Cresting waves ? microscopic salt crystals Rising air currents ? lower air Tadiabatic Salt crystals seed condensation. Rainfall snares soluble gases, feeds Life, erodes mountains, and returns to the sea. But, as everything is connected… Anthropogenic particulates influence where it rains, and downwind it doesn’t. Anthropogenic combustion influences what the rain dissolves and bombards. H2O, the universal solvent, brings acid rain. Global Warming shifts precip. patterns. Redistributes coastlines and grain belts. Feast famine migrates on the globe. Acid Rain Natural Acidity, CO2(aq) PCO2 = 370 ppmv, KH, Ka1 yield pH 5.6 SO3 N2O5 are strong acid anhydrides. Vulcanism, sour crude, and ore smelting produce