Epoxy Curing Chemistry Neo Chemical环氧固化化学新化学.pptVIP

JBC 11/1/01 11/1/01 Cross-linking = Curing Reactive Sites Amine Reactions Linear Mw build-up Amine Reactions followed by Cross-linking Avoid vitrification Amine Reactions possible tertiary amine catalysed hydroxyl-cure temperature helps Crosslink Density Bisphenol-A epoxy resinsInfluence of molecular weight of epoxy resin on key properties Amine Content Calculation Example Amine Hydrogen Equivalent Weight [ AHEW ] = 146 / 6 = 24 g / eq Amine content = 1000 / 24 = 42 eq / kg In order to cure100 grams of resin with EEW = 200 g / eq one would need: How to calculate Mixing-ratio Amine Hydrogen Equivalent Weight [ AHEW ] Epoxy Equivalent Weight [ EEW ] Amount of hardener needed per 100 g of epoxy resin Example Polypox H 043 : AHEW = 115 [ex. UPPC] D.E.R.? 331 epoxy resin : EEW = 188 Theoretical amount of hardener needed per 100 g of D.E.R. 331 epoxy resin Mixing and Pot-life Mixing Quasi all ambient cure epoxy coatings are 2 pack systems. Excellent mixing of the epoxy with the hardener components and an accurate dosing are critical to achieve the expected performances Pot life Amount of time available to apply the product after mixing. Pot life depends also on the temperature and amount of product. Induction time With some systems, an induction time is required. Induction prevents blooming Dow is “NOT” a Curing Agent supplier !!! Toine Dinnissen / March 27th 2007 Page * NEO Chemical Seminar 2007 JBC 11/1/01 O CH3 CH3 O O O CH3 CH3 O O CH2 OH CH CH2 N Reaction via the OH-group[s] Resole, Amine-formaldehyde resins Elevated Temperature Polyisocyanates Room Temperature Reaction via the Epoxy-groups Catalytic Chemical Addition-reactions Elevated Temperature Acids: Anhydrides, Phenols Base: Amines Room Temperature Polysulphides } O CH3 CH3 O OH NH2 N CH2 H OH CH2 NH2 N H O CH3 CH3 O O O NH2 NH2 NH2 NH2 + + O CH3 CH3 O OH N CH2 H OH CH2 N HO CH2 O O CH3 CH3 O OH NH2 N CH2 H OH CH2 NH2 N H O CH3 CH3 O O + O CH3 CH3 O O + O