机电能量应用之材料制作.docVIP

機電能量應用之材料製作 胡伯僑、易崇皓、陳振杰 摘要 機電材料，就是能將機械能與電能作互相轉換的材料，鈣鈦礦(ABO3)結構之鋯鈦酸鉛系列擁有良好的機電特性，但若要具有良好機電換能，柱狀的陣列結構可增加其機電能轉換效率。利用二氧化鈦奈米管陣列為基礎，希望填充鋯、鉛成份以與二氧化鈦形成鋯鈦酸鉛的陣列結構為目標。初步進行填充鍶、鋇、鉛成份研究，探討其與二氧化鈦奈米管的反應晶相形成與微結構變化。實驗顯示可以在二氧化鈦奈米管陣列上生成鈣鈦礦結構薄膜，但由於二氧化鈦奈米管的小管徑，實驗也比較幾種溶液注入法如水溶液滴入法、有機溶液滲入法與旋轉塗佈法等定向所需的元素進入奈米管中。 Application of mechanical and electrical energy production materials HU Bo-Ciao, YI Chong-Hao, CHEN Jen-Jay Energy Materials Investigated by Microwaves Laboratory, Department of Marine Engineering, National Taiwan Ocean University, No.2, Beining Rd., Jhongjheng District, Keelung City 202, Taiwan, ROC Abstract Mechanical and electrical materials, is able to mechanical energy and power for cross-conversion materials, perovskite (ABO3) PZT structure of the series have good mechanical and electrical properties, but to have good electrical and mechanical transducer, the cylindrical array structure Electrical and Mechanical Services to increase its conversion efficiency. Use of titanium dioxide nanotubes array as based, filled with hope that the zirconium, lead elements and titanium dioxide to form PZT array structure as the goal. Initially carries on the packing strontium, barium, lead element of a study on its titanium dioxide nanotubes with the response phase formation and micro-structural changes. Experiments showed that in the titanium dioxide nanotubes arrays generate perovskite films, but because of titanium dioxide nanotubes of small diameter, relatively few experimental solution injection method such as infusion solution, organic solvents into method, spin coating of the required elements, such as orientation into the nanotubes.  一、緒論 1.1什麼是壓電材料 鐵電材料具有優越的介電性、鐵電性、壓電性及焦電性