用于荧光标记的ZnSSiO2复合结构光学特性的研究.pdfVIP

摘 要 ZnS 纳米晶作为典型的半导体纳米材料，在光显示器、光催化、生物标记等领域有 重要的应用前景。本论文针对团聚现象及表面性质对ZnS 纳米材料发光性质的影响， 研究了SiO 修饰的ZnS 及ZnS:Mn 纳米晶的光学性质，并获得了ZnS 基纳米复合材料 2 生物荧光探针。主要结果如下： （1）制备ZnS/SiO 复合材料并研究了其光学性质的变化。结果表明，以SiO 包覆 2 2 在ZnS 纳米晶表面，可有效抑制粒子间的团聚，进而实现对其445 nm 处发光的增强， 对粉末样品其发光强度可增强 17.5 倍。 （2 ）获得了ZnS:Mn/SiO2 纳米复合材料，对比研究了ZnS 、ZnS:Mn 及ZnS:Mn/SiO2 的光学性质。结果表明，SiO 包覆同样可实现ZnS:Mn 纳米晶位于445nm 附近的发光 2 的增强，但会导致575 nm 处Mn 离子相关的发光强度下降。 （3 ）分别构建了基于ZnS/SiO2 及ZnS:Mn/SiO2 纳米复合材料的生物荧光探针。结 果表明，基于复合材料的生物探针很好的保留了纳米材料的光学特性，可进一步应用 于相关生物分子的检测。 关键词：ZnS; SiO ; 团聚; 光学性质; 荧光探针; 2 ABSTRACT ZnS nanocrystal, as a typical semiconductor nanomaterial, has important applications in the fields of optical display, photocatalysis, and biomedical label. This thesis focuses on the influence of agglomeration and surface properties on the optical properties of ZnS nanocrystals. The optical properties of SiO2 modified ZnS and ZnS:Mn nanocrystals were investigated. ZnS-based fluorescent biolabels were finally obtained.The main results are as follow: (1) ZnS/SiO nanocomposites were prepared and the optical properties were studied. The 2 results show that SiO2 coating can effectively inhibit the aggregation of the nanoparticles, which enhance the luminescence of ZnS nanocrystals at 445 nm. In addition, the luminescence intensity of the powder samples can be further enhanced to17.5 times. (2) ZnS:Mn/SiO2 nanocomposites were obtained, and the optical properties of ZnS, ZnS:Mn, and ZnS:Mn/SiO2 were compared. The results show that SiO2 coating can enhance the luminescence of ZnS:Mn nanocrystals at 445 nm, but will result in the decrease of the Mn