以次磷酸钠为还原剂制备片状铜粉.pdfVIP

以次磷酸钠为还原剂制备片状铜粉 摘要：采用液相化学还原法,在PEG600存在的情况下，以NaH PO ●H O为还原剂， 2 2 2 制备了粒径 ～ ，厚度 ～ ，表面光滑的片状超细铜粉。实验得出 10 40 μm 1.5 2.5 μm 优化工艺条件为: CuSO 浓度0.2 mol/L ，NaH PO 浓度0.14mol/L ，模板剂PEG600 4 2 2 体积分数加入量1%-3%，温度80℃，pH0.3～0.7 。粉末XRD谱图和SEM 电镜分析 显示，形状为较为规则的片状铜粉。 关键词：片状铜粉；PEG；液相还原 Preparation of Flake-shaped Copper Particles by using NaH PO as reductant 2 2 1,2 2 2 CHEN Ming-wei ，ZHU Yong-ping ，ZHANG Wei-gang (1. Graduate University of Chinese Academy of Sciences, Beijing 100049, China 2. State Key Laboratory of Multi-phase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China) Abstract ：The flake-shaped crystalline copper particles with 10～40 μm in diameter and 1.5～2.5 μm in thickness were prepared by using liquid phase reduction method with NaH PO ●H O as reducing agent and PEG600 as template. 2 2 2 The effects of pH value of reductive solution, reaction temperature, concentration of CuSO4 and volume of PEG600 on the preparation of flake-shaped copper particles were studied emphatically．The optimum conditions were obtained as follows: the concentration of CuSO and NaH PO were 0.2 mol/L and 0.14 mol/L, 4 2 2 respectively, the volume ratio of PEG600 0.1%～3%, the reaction temperature 80℃,and the pH value 0.3～0.7. The product prepared is proved to be pure flake-shaped copper particles through the analysis of XRD and TEM ． Key words ：flake-shaped copper particles ；PEG600; liquid phase reduction method 作者简介：陈明伟（1984-）, 男, 山东省泰安市人，硕士研究生，化学工程专业；朱永平，通讯联系人，Tel: 010E-mail: ypzhu@home