The impact of zinc oxide particle morphology as an antimicrobial and when incorporated in poly(3-hydroxybutyrate-co-3-hydroxyvalerate) films for food packaging and food contact surfaces applications.pdfVIP
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The impact of zinc oxide particle morphology as an antimicrobial and when incorporated in poly(3-hydroxybutyrate-co-3-hydroxyvalerate) films for food packaging and food contact surfaces applications.pdf
food and bioproducts processing 1 0 1 ( 2 0 1 7 ) 32–44
Contents lists available at ScienceDirect
Food and Bioproducts Processing
journal homepage: /locate/fbp
The impact of zinc oxide particle morphology as an antimicrobial and when incorporated in poly(3-hydroxybutyrate-co-3-hydroxyvalerate) ?lms for food packaging and food contact surfaces applications
J.L. Castro-Mayorga a, M.J. Fabra a, A.M. Pourrahimi b, R.T. Olsson b, J.M. Lagaron a,?
a Novel Materials and Nanotechnology Group, Institute of Agrochemistry and Food Technology (IATA), CSIC, 46980 Valencia, Spain b KTH Royal Institute of Technology, School of Chemical Science and Engineering, Fibre and Polymer Technology, SE-100 44 Stockholm, Sweden
article info
Article history: Received 11 January 2016 Received in revised form 12 October 2016 Accepted 16 October 2016 Available online 24 October 2016
Keywords: ZnO PHBV Antimicrobial activity Electrospinning Active Packaging Food contact surfaces
abstract
In this work, zinc oxide (ZnO) micron and nano sized-particles with different morphologies were synthesized by aqueous precipitation and evaluated as antimicrobial agents against foodborne pathogens. The most effective bactericide system was selected to prepare active poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) ?lms by three different methods (i) direct melt-mixing, (ii) melt-mixing of preincorporated ZnO into PHBV18 (18 mol% valerate content) ?ber mats made by electrospinning, and, (iii) as a coating of the annealed electrospun PHBV18/ZnO ?ber mats over compression molded PHBV. Results showed that ZnO successfully improved the thermal stability of the PHBV18, being the preincorporation method the most ef?cient in mitigating the negative impact that the PHBV18 had on the thermal stability, barrier and optical properties of the PHBV ?lms. Similar behavior was found for the coating structure although this ?lm showed effective and prolonged antibacterial activity against Listeria monocytogenes. This study hi
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