奈米碳管与场发射显示器.ppt

奈米碳管與場發射顯示器 應用力學研究所 林嘉龍 Outline 奈米碳管的出現 重要的發展技術論文 CNT的特性與應用 CNT-FED CNT-FED現況與市場分析 CNT-FED相關技術與瓶頸 結論 奈米碳管的出現 Carbon nanotubes are fullerene-related structures which consist of graphene cylinders closed at either end with caps containing pentagonal rings. They were discovered in 1991 by the Japanese electron microscopist Sumio Iijima who was studying the material deposited on the cathode during the arc-evaporation synthesis of fullerenes. He found that the central core of the cathodic deposit contained a variety of closed graphitic structures including nanoparticles and nanotubes, of a type which had never previously been observed. A short time later, Thomas Ebbesen and Pulickel Ajayan, from Iijimas lab, showed how nanotubes could be produced in bulk quantities by varying the arc-evaporation conditions. This paved the way to an explosion of research into the physical and chemical properties of carbon nanotubes in laboratories all over the world. 1991年，日本NEC Iijima博士在TEM下發現到碳奈米管的影像圖形 近十年來的重要發展論文 Carbon Nanotubes - A Time Line 1991 ???Discovery of multi-wall carbon nanotubes ?[Helical microtubules of graphitic carbon, S. Iijima, Nature 354, 56 (1991)] 1992 ???Conductivity of carbon nanotubes ?[Are fullerene tubules metallic?, J. W. Mintmire, B. I. Dunlap and C. T. White, Phys. Rev. Lett. 68, 631 (1992)New one-dimensional conductors - graphitic microtubules, N. Hamada, S. Sawada and A. Oshiyama, Phys. Rev. Lett. 68, 1579 (1992)Electronic structure of graphene tubules based on C60, R. Saito, M. Fujita, G. Dresselhaus and M. S. Dresselhaus, Phys. Rev. B 46, 1804 (1992)] 1993 ???Structural rigidity of carbon nanotubes ?[Structural Rigidity and Low Frequency Vibrational Modes of Long Carbon Tubules, G. Overney, W. Zhong, and D. Tománek, Z. Phys. D 27, 93 (1993)] 1993 ???Synthesis of single-wall nanotubes ?[Single-shell carbon nanotubes of 1-nm diameter, S Iijima and T Ichihashi Nature, 363, 603 (1993)Cobalt-catalysed growth of carbon nanotubes with single-a