小分子溶剂在聚乙烯膜中无限稀释扩散系数的测定.pdf

A016 小分子溶剂在聚乙烯膜中无限稀释扩散系数的测定 姜珍 李继定? 赵之平 陈翠仙 （清华大学化工系膜技术工程研究中心，北京，100084） 摘 要 气相色谱法研究小分子溶剂与聚合物材料之间的相互作用是一种快速、准确、方便的方法， 该方法可以测量多种小分子溶剂在聚合物中的溶解、扩散行为。本文通过气相色谱法测定了6种小分 子溶剂（正庚烷、正壬烷、正癸烷、苯、甲苯和乙苯）在固定液聚乙烯中的保留时间和半峰宽，运用 van Deemter 模型进行数据处理，得到上述 6 种小分子在聚乙烯膜中的无限稀释扩散系数，获得了有 意义的结果。 关键词 气相色谱 小分子溶剂 低密度聚乙烯 扩散系数 MEASUREMENT OF DIFFUSION COEFFICIENTS OF THREE SOLVENTS AT INFINITE DILUTION IN POLYETHYLENE Jiang Zhen Li Jiding Zhao Zhiping Chen Cuixian (Membrane Technology and Engineering Research Center, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstact Gas chromatography is a new, fast, accurate and convenient technique to study the relationship between small molecule solvents and polymer membrane materials. Many parameters of dissolution and diffusing characters of a small molecule in a polymer can be measured by this method. The rentention times and the peak widths at half-height of six small molecule solvents (n-heptane , n-nonane , n-decane , benzene , toluene and ethylbenzene) in the stationary phase of polyethylene were measured. The diffusion coefficients of the small molecule solvents at infinite dilution were calculated with van Deemter equation. The graphs plotted according to the results of the diffusion coefficients of the six solvents at infinite dilution vs temperatures were agreement with the Arrhenius equation. The variance in the diffusion coefficients at infinite dilution of six small molecule solvents was analyzed according to the differences in molecular mass. Keywords Gas chromatography, Small molecule solvent, Low density polyethylene, Diffusion coefficient 引 言 随着高分子材料研究和应用的日益广泛，小分子与高分子相互作用参数研究显示出重 ?通讯联系人：李继定（1955－），男，博士，清华大学化工系教授， 基金项目：国家 863 项目（No.2003AA328020 ）；国家973 项目（No