碳纳米管连续碳纤维增强环氧树脂复合材料的微观结构与力学性能研究.pdfVIP

170 1 1991 Iijima Ni [1] () ( ) [2-9] Fe Co 1.8 TPa 14.2GPa[10] 2 2.1 1100~1200 2.2 / T300 171 60 2.3 INSTRON 1121 TEM JEOL JEM 1200EX STEREOSCAN 250 MK3 CAMBRIDGE 3 T300 GB3356 82 100KV 3.1 / 1 50~1000μm 2 3 / 20~50 SEM 10~30 3 (a) 1 (a) Fig.1 TEM image of carbon nanotubes 100nm (b) (b) 172 2 SEM Fig.2 SEM images of transects of carbon nanotube and carbon fiber reinforced composites 3.2 / 4/ 0 1430Mpa 118GPa 1wt 1450MPa 166GPa 3wt 1780MPa 164GPa 5wt 1120MPa 126GPa 3wt 3 SEM Fig.3 SEM images of vertical section of carbon nanotube and carbon fiber reinforced composites 173 Flexural strength (Mpa) Modulus (Gpa) 2000 1800 1600 1400 1200 1000 01 23 45 Carbon nanotube content (wt%) 200 180 160 140 120 100 0 1 23 4 Carbon nanotube content (wt%) 5 4 Fig.4 Flexural strength and modulus changes of composites with carbon nanotube contents in epoxy resin matrix 3-12 T300 / DMTA 3-13 /T300 DMTA 3-12 3-13 3-14 /T300 3-14 tanδ 4 118GPa 5wt 3wt 1wt 1120MPa 0 1780MPa 126GPa 1450MPa 164GPa 1430Mpa 166GPa 3wt [1] Iijima S. Helical microtubules of graphitic carbon. Nature, 1991, 354:56-58. [2] Jones J M, Malcolm R P, Thomas K M, et al. The anode deposit formed during the carbon-arc evaporation of graphite for the synthesis of fullerenes and carbon nanotubes. Carbon, 1996, 34(2):231-237 [3] Yacaman M J, Yoshida M M, Rendon L. Catalytic growth of carbon microtubules with fulleren structure. Appl Phys Lett, 1993, 62(2):202-206 [4] Guo T, Nikolaev P, Thess A, et al. Catalytic growth of single-waled nanotubes by laser vaporization. Chem Phys Lett, 1995, 243: 49-56 [5] Cho W S, Hamada E, Kondo Y et al. Synthesis of carbon nanotubes from bulk polymer. Appl Phys Lett, 1996, 69(2): 278-283. 174 [6] Richter H, Hernadi K, Caudano R, et al. Formation of nanotubes in low pressure hydrocarbon flames. Carbon, 1996, 34(11): 427-435 [7] Chernozatonskii L A, Kosakovskaja I J, Fedorov E A, et al. New carbon tubelite-ordered film structure of muitilayer nanotubes. Physics Letters A, 1995, 197(1): 40-43 [