扩散渗析法应用于石煤提钒酸浸液预处理研究.doc

扩散渗析法石煤提钒酸浸液研究 (1.武汉科技大学 资源与环境工程学院，武汉 430081；2.湖北省页岩钒资源高效清洁利用工程技术研究中心，武汉 430081；3.钒资源高效利用湖北省协同创新中心，武汉 430081 摘要：采用扩散渗析法对石煤提钒酸浸液进行预处理，考察料液(酸浸液)流速、水料(水/酸浸液)流速比对处理后液pH、硫酸回收率、水反渗率、离子截留率的影响。研究表明，在料液流速12 mL/min、水料流速比1.0~1.1的最佳条件下，预处理后的酸浸液pH由0.04提高到1.0，硫酸回收率为71.12%，水反渗率为14.95%，钒截留率为95.50%。主要杂质离子铝、铁、镁、钾、氟、磷、硫的截留率分别为99.04%、97.37%、98.01%、85.12%、98.33%、91.16%、69.96%。扩散渗析预处理实现了酸浸液pH的提升，同时回收酸可以重新利用。 关键词：扩散渗析；石煤；酸浸液；预处理 中图分类号：TF841.3 文献标志码：A 文章编号：1007-7545（2017）04-0000-00 Application of Diffusion Dialysis Method to Pretreat Stone Coal Acid Leaching Solution WANG Kui1,2, ZHANG Yi-min1,2,3, HUANG Jing1,2,3, LIU Tao1,2,3, WANG Jing-peng1,2 (1. College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, China; 2. Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource, Wuhan 430081, China; 3. Hubei Provincial Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources, Wuhan 430081, China) Abstract：Diffusion dialysis method was applied to pretreat stone coal acid leaching solution. Effects of feed flow rate, flow rate ratio (water/feed) on pH value of dialysate, sulfuric acid recovery, water reverse osmosis rate, and ions rejection were investigated. The results show that the optimum operation conditions include feed flow rate of 12 mL/min and flow rate ratio of water to feed of 1.0~1.1. Under the optimum operation conditions, pH value of acid leaching solution pretreated by diffusion dialysis rises to 1.0 from 0.04, sulfuric acid recovery is 71.12%, water reverse osmosis rate is 14.95%, and vanadium rejection is 95.50%. Rejection of impurity ions, such as Al, Fe, Mg, K, F, P, S is 99.04%, 97.37%, 98.01%, 85.12%, 98.33%, 91.16%, and 69.96% respectively. pH value of acid leaching solution is improved by pretreatment of diffusion dialysis. Recovered acid can be reused. Key words：diffusion dialysis; stone coal; acid leaching solution; pretreat