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Self-Assembled 3D Flowerlike Iron Oxide Nanostructures and.pdf

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Self-Assembled 3D Flowerlike Iron Oxide Nanostructures and

DOI: 10.1002/adma.200600504 Self-Assembled 3D Flowerlike Iron Oxide Nanostructures and Their Application in Water Treatment** By Liang-Shu Zhong, Jin-Song Hu, Han-Pu Liang, An-Min Cao, Wei-Guo Song, and Li-Jun Wan* 3D nanostructures have attracted much attention because of their unique properties and potential applications.[1–13] The simplest synthetic route to 3D nanostructures is probably self- assembly, in which ordered aggregates are formed in a sponta- neous process.[2] However, it is still a big challenge to develop simple and reliable synthetic methods for hierarchically self- assembled architectures with designed chemical components and controlled morphologies, which strongly affect the prop- erties of nanomaterials. Iron oxides have been extensively studied in diverse fields including catalysis,[14–16] environment protection,[17–23] sensors,[24] magnetic storage media,[25] and clinical diagnosis and treatment.[26] Various iron oxide struc- tures, such as nanocrystals,[27–29] particles,[30,31] cubes,[32] spin- dles,[33] rods,[34,35] wires,[36] tubes,[37] and flakes,[38] have been successfully fabricated by a variety of methods. However, the self-assembly of these low-dimensional building blocks into complex 3D ordered nanostructures is still considerably more difficult. In order to further understand the mechanism of self-organization and expand the applications of iron oxide nanomaterials, self-assembled iron oxide 3D nanostructures need to be explored in more detail. Herein, we report the synthesis of novel 3D flowerlike iron oxide nanostructures by an ethylene glycol (EG)-mediated self-assembly process. Such a method has been adopted pre- viously for the preparation of V2O5 hollow microspheres, [7] SnO2 nanowires, [39,40] and cobalt alkoxide disk-shaped parti- cles.[41] However, in these previous studies, expensive metal organic compounds including acetates, oxalates, or acetylace- tonates were used as metal-ion sources; in this study we used ferric chlor