Exercises-Chapter 12-配位化学基础.docVIP

Excercises Chapter 12 配位化合物基础 专业、班级 学号 姓名 Ⅰ. ?Fill in the blanks 1. The name of [Cr(H2O)(en)(C2O4)(OH)] is ; the coordination sphere is ; its oxidation state of Cr is ; its coordination number is . 2. The observed magnetic moment of [Ni(NH3)6]2+ is 3.2 BM. The hybridization of the complex is . The complex is known as orbital complex and the expected geometry is . 3. The formation constant, Kf is 2.1?013 for [Cu(NH3)4]f2＋ and 2.9×109 for [Zn(NH3)4]2＋. The reaction, [Cu(NH3)4]2＋＋Zn2＋ [Zn(NH3)4]2＋＋Cu2＋, is . Ⅱ. Multiple Choice (only one is correct) ( )1. Amongst the following ions which one has the highest paramagnetism? (a) [Cr(H2O)6]3+ (b) [Fe(H2O)6]2+ (c) [Cu(H2O)6]2+ (d) [Zn(H2O)6]2+ ( )2. The central metal oxidation state, coordination number, and the overall charge on the complex ion in NH4[Cr(NH3)2(NCS)4] are, respectively, (a) -3, 4, -1 ?(b)+1, 4, +1 ?(c) +3, 6, -1 ?(d) -3, 2, -1 ( )3. The coordination number of Co3+ in the [Co(en)(C2O4)2]- complex is (a) 4? (b) 6? (c) 2? (d) 5 ( )4. For [CoF6]3- (F- is a weak-field ligand.)the number of unpaired electrons would is. ? (a) 5? (b) 6? (c) 4? (d) 3? ( )5. When we add NH3? H2O into the half cell reaction, Cu2+ + 2 e-Cu, the value of φθ(Cu2+/Cu) will (a) increase (b) remain the same (c) decrease (d) depend on the NH3? H2O concentration ( )6. [Mn(CN)6]4- (25Mn) is a low spin complex, so, the unpaired electrons and hybridization type of Mn2+ are (a) 5, sp3d2 (b) 0, sp3d2 (c) 1, d2sp3 (d) 0, d2sp3 ( )7. In the following cases, there are two possible choices when electrons are filled in d orbitals of the central atom in an octahedral field (八面体场)d 5