污染源区结构特征对 Tween 80去除 DNAPL 效果的影响.pdfVIP

中国环境科学 2016,36(7)：2035~2042 China Environmental Science 污染源区结构特征对 Tween 80 去除 DNAPL 效果的影响 * * 郑 菲,高燕维,孙媛媛,徐红霞,施小清 ,吴吉春 (南京大学地球科学与工程学院水科学系,表生地球化学教育 部重点实验室,江苏 南京 210023) 摘要：选择四氯乙烯(PCE)作为特征污染物,通过二维砂箱实验探究 3 种介质情景中,污染源区结构特征对 Tween 80 冲洗去除 PCE 的影响. 采用透射光法监测 PCE 的运移及去除过程,定量测定 PCE 的饱和度.进而采用不连续的离散状与连续的池状 PCE 体积比(GTP)定量表征污 染源区结构特征.结果表明,PCE 在含透镜体介质中运移时,运移路径延长,离散状 PCE 增多.离散状 PCE 与 Tween 80 溶液的有效接触面积较 大,被优先溶解去除,而细砂层上部的污染池的比表面积和接触面积较小,溶解能力有限,远比运移路径上的 PCE 难以去除.此外,初始离散状 PCE 较多,GTP 较大,有利于池状 PCE 溶解转变为离散状 PCE,PCE 去除率增大.因此对于实际污染场地,需要详细分析 DNAPLs 污染源区结 构特征,以助于评估表面活性剂冲洗技术的修复效率及试剂消耗. 关键词：PCE；透射光法；污染源区结构；Tween 80；GTP 中图分类号：X523 文献标识码：A 文章编号：1000-6923(2016)07-2035-08 The influence of source-zone architecture on DNAPL removal by Tween 80 flushing. ZHENG Fei, GAO Yan-wei, SUN Yuan-yuan, XU Hong-xia, SHI Xiao-qing*, WU Ji-chun* (Key Laboratory of Surficial Geochemistry, Ministry of Education, School of Earth Sciences and Engineering, Hydrosciences Department, Nanjing University, Nanjing 210023, China). China Environmental Science, 2016,36(7)：2035~2042 Abstract：The PCE was selected as representative DNAPLs. Three 2-D sandbox experiments were conducted to investigate the effect of source-zone architecture on the PCE by Tween 80flushing. The light transmission method was used to monitor the migration and remediation processes of PCE within the sandboxes, and quantitatively measure PCE saturation distribution. The ratio of volume of PCE ganglia to the volume of pools (GTP) was used to quantify source-zone architecture, and the effect of GTP on the PCE removal was evaluated. Experimental results showed that when PCE migrated in the po