Film test the applicability of.docVIP

 PAGE \* MERGEFORMAT 13 Film test the applicability of [Keywords:] film test; applicability; Organic Chemistry Film test is a well-known in organic chemistry experiment. Experimental film set in 1848, but in domestic and international organic chemistry textbooks and other literature on the identification of aldehydes and ketones film test for the applicability of different argument, summed up, roughly following several theories: film reagents with aldehydes to generate Red cuprous oxide precipitation, and one not react. Film reagent can be identified aldehydes and ketones; film reagent and the reaction of aliphatic aldehydes with aromatic aldehydes do not respond, not react with ketones. Film reagent can be identified aliphatic aldehydes and aromatic aldehydes and ketones; only said that water-soluble aliphatic aldehydes can be restored film reagents; argument is not clear. “Typical aliphatic aldehydes react”, “Some aromatic aldehydes do not respond”; the United States, “Chemical Education” magazine in 1960 4 Ralph Daniels, who will be the response is divided into three categories: first, generate colorless solution, while there yellow to red cuprous oxide precipitate, fall into this category of compounds are glucose and other reducing sugars, α-hydroxy-2 has been aldehyde, glyoxal and acetone. Second, the occurrence of a complex change, build red or dark brown adhesive deposition. The upper liquid can be blue, green, brown, yellow or orange. Precipitation is not a cuprous oxide. The compounds fall into this category are: acetaldehyde, crotonaldehyde (2 - butene aldehyde), cinnamic aldehyde, 3 - hydroxybutyrate aldehyde. Third, the blue reagent solution remain unchanged, with or without immiscible organic layer. Fall into this category of compounds are benzene, formaldehyde, general aromatic aldehyde, isobutyraldehyde and acetone. In view of this situation, to the organic chemistry teaching in no small difficulties, and the teaching experiment also