Naringin imprinted preparation and application of sensor.doc

 PAGE \* MERGEFORMAT 17 Naringin imprinted preparation and application of sensor Of: Ma Xiuling Chen Ri-Yao ZHENG Xi Chen Chen Zhen [Abstract] o-amino phenol as the monomer, the electrochemical activity of naringin-free as the template molecule, by cyclic voltammetry (scan rate 100 mV / s scan back and forth in the carbon electrode 30, with the recognition that electropolymerization Naringin-sensitive membrane molecular function. by scanning electron microscopy (SEM, X-ray total reflection (XRR and electrochemical characterization of the imprinted sensor. The results show that the imprinted and non-imprinted film sensor sensitive to film morphology and electrical chemical properties are quite different. naringin this sensor has good selectivity, fast response (30 s), at 6.0 × 10-5 ~ 1.4 × 10-4 mol / L range of linear relationship and good reproducibility (RSD = 1.8%, n = 5), the sensor detection limit of naringin 1.6 × 10-5 mol / L. [Keywords:] naringin, molecular imprinting, sensors, o-Aminophenol Abstract The sensor of naringin (NG), a non-electroactive substance, was prepared based on the molecular imprinting technique.Using cyclic voltammetry technique (scan rate is 100 mV / s), the naringin imprinting sensitive film, poly-ο-aminophenol was coated on the surface of a graphite electrode in the presence of naringin which was considered as the template, and characterized by SEM and X-ray reflective spectrophotometry (XRR). Using K3Fe (CN) 6 as an electroactive marker, the electrochemical properties of the NG sensor were investigated by CV, electrochemical impedance spectroscopy (EIS), differential pulse voltammmetric and chronoamperometric.The results showed that the imprinted electrode was significantly different from the non-imprinted electrode in morphologies and electrochemical properties, and a linear relationship between the peak current and the naringin concentration was found in the range of 6.0 × 10-5-1.4 × 10-4 mol / L with a detection li